Validating an endoperoxide as a key intermediate in the biosynthesis of elysiapyrones

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dc.contributor.authorDiaz-Marrero, Ana R.
dc.contributor.authorCueto, Mercedes
dc.contributor.authorD'Croz, Luis
dc.contributor.authorDarias, Jose
dc.date.accessioned2011-02-09T20:02:34Z
dc.date.available2011-02-09T20:02:34Z
dc.date.issued2008
dc.description.abstractCompounds 1-3 isolated from Elysia diomedea are described. Compound 1 is an endoperoxide derivative of elysiapyrone A. The biomimetictype transformation of compound 1 to elysiapyrone A catalyzed by neutral base transformed the endoperoxide to a vicinal diepoxide, thus suggesting the endoperoxide as a key intermediate in the biosynthesis of elysiapyrone A. A biogenetic pathway for their formation involving a cycloaddition of singlet oxygen to a polypropionate alkenyl open chain is proposed.
dc.format.extent3057–3060
dc.identifier.citationDiaz-Marrero, Ana R., Cueto, Mercedes, D'Croz, Luis, and Darias, Jose. 2008. "<a href="https://repository.si.edu/handle/10088/11855">Validating an endoperoxide as a key intermediate in the biosynthesis of elysiapyrones</a>." <em>Organic letters</em>, 10, (14) 3057–3060. <a href="https://doi.org/10.1021/ol8010425">https://doi.org/10.1021/ol8010425</a>.
dc.identifier.urihttp://hdl.handle.net/10088/11855
dc.relation.ispartofOrganic letters 10 (14)
dc.titleValidating an endoperoxide as a key intermediate in the biosynthesis of elysiapyrones
dc.typearticle
sro.description.unitSTRI
sro.identifier.doi10.1021/ol8010425
sro.identifier.itemID74257
sro.identifier.refworksID7299
sro.identifier.urlhttps://repository.si.edu/handle/10088/11855

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