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Leptogorgolide, a biogenetically interesting 1,4-diketo-cembranoid that reinforces the oxidation profile of C-18 as taxonomical marker for octocorals
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| dc.contributor.author | Diaz Marrero, Ara R. | |
| dc.contributor.author | Porras, Gina | |
| dc.contributor.author | Cueto, Mercedes | |
| dc.contributor.author | D'Croz, Luis | |
| dc.contributor.author | Lorenzo, Manuel | |
| dc.contributor.author | San-Martin, Aurelio | |
| dc.contributor.author | Darias, Jose | |
| dc.date.accessioned | 2011-04-21T16:39:02Z | |
| dc.date.available | 2011-04-21T16:39:02Z | |
| dc.date.issued | 2009 | |
| dc.identifier | 0040-4020 | |
| dc.identifier.citation | Diaz Marrero, Ara R., Porras, Gina, Cueto, Mercedes, D'Croz, Luis, Lorenzo, Manuel, San-Martin, Aurelio, and Darias, Jose. 2009. "<a href="https://repository.si.edu/handle/10088/15888">Leptogorgolide, a biogenetically interesting 1,4-diketo-cembranoid that reinforces the oxidation profile of C-18 as taxonomical marker for octocorals</a>." <em>Tetrahedron</em>, 65, (31) 6029–6023. <a href="https://doi.org/10.1016/j.tet.2009.05.068">https://doi.org/10.1016/j.tet.2009.05.068</a>. | |
| dc.identifier.uri | http://hdl.handle.net/10088/15888 | |
| dc.description.abstract | The cembranoid 1 and the furanocembranolides 2–4 along with the known pukalide were isolated from Leptogorgia sp. and their structures determined spectroscopically. The 1,4-diketo-cembranoid 1 follows an oxidation pattern of C-18 that reinforces the concept of oxidation profile of C-18 as taxonomical marker for octocorals. The co-occurrence within a species of furanocembranolide/1,4-diketo-cembranoid congeners 1/2–4 raises the question about which one is the biogenetic precursor. A biogenetic pathway is proposed. | |
| dc.format.extent | 6029–6023 | |
| dc.relation.ispartof | Tetrahedron 65 (31) | |
| dc.title | Leptogorgolide, a biogenetically interesting 1,4-diketo-cembranoid that reinforces the oxidation profile of C-18 as taxonomical marker for octocorals | |
| dc.type | article | |
| sro.identifier.refworksID | 7168 | |
| sro.identifier.itemID | 78957 | |
| sro.description.unit | NH-EOL | |
| sro.description.unit | STRI | |
| sro.identifier.doi | 10.1016/j.tet.2009.05.068 | |
| sro.identifier.url | https://repository.si.edu/handle/10088/15888 |
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STRI Staff Publications [3772]
A collection of scientific publications by STRI staff.
