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Leptogorgolide, a biogenetically interesting 1,4-diketo-cembranoid that reinforces the oxidation profile of C-18 as taxonomical marker for octocorals

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dc.contributor.author Diaz Marrero, Ara R. en
dc.contributor.author Porras, Gina en
dc.contributor.author Cueto, Mercedes en
dc.contributor.author D'Croz, Luis en
dc.contributor.author Lorenzo, Manuel en
dc.contributor.author San-Martin, Aurelio en
dc.contributor.author Darias, Jose en
dc.date.accessioned 2011-04-21T16:39:02Z
dc.date.available 2011-04-21T16:39:02Z
dc.date.issued 2009
dc.identifier.citation Diaz Marrero, Ara R., Porras, Gina, Cueto, Mercedes, D'Croz, Luis, Lorenzo, Manuel, San-Martin, Aurelio, and Darias, Jose. 2009. "<a href="https%3A%2F%2Frepository.si.edu%2Fhandle%2F10088%2F15888">Leptogorgolide, a biogenetically interesting 1,4-diketo-cembranoid that reinforces the oxidation profile of C-18 as taxonomical marker for octocorals</a>." <em>Tetrahedron</em>. 65 (31):6029&ndash;6023. <a href="https://doi.org/10.1016/j.tet.2009.05.068">https://doi.org/10.1016/j.tet.2009.05.068</a> en
dc.identifier.uri http://hdl.handle.net/10088/15888
dc.description.abstract The cembranoid 1 and the furanocembranolides 2 4 along with the known pukalide were isolated from Leptogorgia sp. and their structures determined spectroscopically. The 1,4-diketo-cembranoid 1 follows an oxidation pattern of C-18 that reinforces the concept of oxidation profile of C-18 as taxonomical marker for octocorals. The co-occurrence within a species of furanocembranolide/1,4-diketo-cembranoid congeners 1/2 4 raises the question about which one is the biogenetic precursor. A biogenetic pathway is proposed. en
dc.relation.ispartof Tetrahedron en
dc.title Leptogorgolide, a biogenetically interesting 1,4-diketo-cembranoid that reinforces the oxidation profile of C-18 as taxonomical marker for octocorals en
dc.type Journal Article en
dc.identifier.srbnumber 78957
dc.identifier.doi 10.1016/j.tet.2009.05.068
rft.jtitle Tetrahedron
rft.volume 65
rft.issue 31
rft.spage 6029
rft.epage 6023
dc.description.SIUnit encyclopedia of Life en
dc.description.SIUnit forces of Change en
dc.description.SIUnit Marine biology en
dc.description.SIUnit Naos Island Laboratories en
dc.description.SIUnit STRI en
dc.citation.spage 6029
dc.citation.epage 6023


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