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Validating an endoperoxide as a key intermediate in the biosynthesis of elysiapyrones
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| dc.contributor.author | Diaz-Marrero, Ana R. | en |
| dc.contributor.author | Cueto, Mercedes | en |
| dc.contributor.author | D'Croz, Luis | en |
| dc.contributor.author | Darias, Jose | en |
| dc.date.accessioned | 2011-02-09T20:02:34Z | |
| dc.date.available | 2011-02-09T20:02:34Z | |
| dc.date.issued | 2008 | |
| dc.identifier.citation | Diaz-Marrero, Ana R., Cueto, Mercedes, D'Croz, Luis, and Darias, Jose. 2008. "<a href="https%3A%2F%2Frepository.si.edu%2Fhandle%2F10088%2F11855">Validating an endoperoxide as a key intermediate in the biosynthesis of elysiapyrones</a>." <em>Organic letters</em>. 10 (14):3057–3060. <a href="https://doi.org/10.1021/ol8010425">https://doi.org/10.1021/ol8010425</a> | en |
| dc.identifier.uri | http://hdl.handle.net/10088/11855 | |
| dc.description.abstract | Compounds 1-3 isolated from Elysia diomedea are described. Compound 1 is an endoperoxide derivative of elysiapyrone A. The biomimetictype transformation of compound 1 to elysiapyrone A catalyzed by neutral base transformed the endoperoxide to a vicinal diepoxide, thus suggesting the endoperoxide as a key intermediate in the biosynthesis of elysiapyrone A. A biogenetic pathway for their formation involving a cycloaddition of singlet oxygen to a polypropionate alkenyl open chain is proposed. | en |
| dc.relation.ispartof | Organic letters | en |
| dc.title | Validating an endoperoxide as a key intermediate in the biosynthesis of elysiapyrones | en |
| dc.type | Journal Article | en |
| dc.identifier.srbnumber | 74257 | |
| dc.identifier.doi | 10.1021/ol8010425 | |
| rft.jtitle | Organic letters | |
| rft.volume | 10 | |
| rft.issue | 14 | |
| rft.spage | 3057 | |
| rft.epage | 3060 | |
| dc.description.SIUnit | Encyclopedia of Life | en |
| dc.description.SIUnit | Forces of Change | en |
| dc.description.SIUnit | Marine biology | en |
| dc.description.SIUnit | Naos Island Laboratories | en |
| dc.description.SIUnit | Panama | en |
| dc.description.SIUnit | STRI | en |
| dc.citation.spage | 3057 | |
| dc.citation.epage | 3060 |
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STRI Staff Publications [3755]
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