re
ics
Hannes K. Brueckner a,b,e,?, Hans
Sidney R. Hemming b, Uwe Marte
a School of Earth and Environmental Sciences, Queens Col
b Lamont?Doherty Earth Observatory, Columbia Universit
c Department of Earth Science, Rice University, Houston, T
d Geosciences Department, University of Houston, Housto
e Department of Earth and Planetary Sciences, American
f Department of Geological and Environmental Sciences, S
istry an
eum of N
Sm?Nd geochronology
Earth and Planetary Science Letters xxx (2009) xxx?xxx
EPSL-09801; No of Pages 8
Contents lists available at ScienceDirect
Earth and Planetar
.e
ARTICLE IN PRESSHP/LT eclogites
strike?slip and subduction zone processes
oblique collisional tectonics
therefore that all serpentinite hosted eclogites along the Motagua fault formed at essentially the same time
in different parts of a laterally extensive Lower Cretaceous forearc subduction system, but subsequently
underwent different histories. The southern assemblages were thrust southwards (present coordinates)
immediately afterHPmetamorphismwhereas the northern associationwas retrograded during a later collision
that thrust it northward at ca. 70 Ma. They were subsequently juxtaposed opposite each other by major strike
slip motion. This model implies that the HP rocks on opposing sides of the Motagua fault evolved along a plate
boundary that underwent both dip slip and strike slip motion throughout the Late Cretaceous as a result of
oblique convergence. The juxtaposition of a convergent and strike slip system means that HP/LT rocks within
serpentinites can be found at depth along much of the modern Guatemala suture zone and its eastward
extension into the northern Caribbean. Both sets of assemblages were exhumed relatively recently by the
uplift of mountain ranges on both sides of the fault caused by movement along a restraining bend. Recent
exhumation explains the apparently lack of offset of surface outcrops along a major strike slip fault.
? 2009 Elsevier B.V. All rights reserved.
1. Introduction
Serpentinite belts exposed on land and containing high pressure/
of ocean basins as part of the Wilson Cycle (Wilson, 1960). Most
sutures were assumed to be perpendicular to convergent directions
since major dip slip motion is required to form HP rocks. However,low temperature (HP/LT) metamorphic rock
nally as occupying the suture zone between
terranes (Hess, 1965; Maekawa et al., 2004) a
? Corresponding author. Lamont-Doherty Earth Obs
Palisades, NY 10964 USA. Tel.: +1 845 365 8388.
E-mail address: hannes@ldeo.columbia.edu (H.K. Bru
0012-821X/$ ? see front matter ? 2009 Elsevier B.V. A
doi:10.1016/j.epsl.2009.04.032
Please cite this article as: Brueckner, H.K.,
fault, Guatemala: A record of Neocomian aEclogites north of the fault give similar Sm?Nd isochron ages (131?126Ma) but otherwise differ in that theyare
strongly overprinted by a lower pressure assemblage and, along with associated HP/LT rocks, give much
younger 40Ar/39Ar ages of 88?55 Ma indicating a later amphibolite facies metamorphic event. We proposeKeywords:g The Pheasant Memorial Laboratory for Geochem
h Department of Mineral Sciences, National Mus
a r t i c l e i n f o
Article history:
Received 2 December 2008
Received in revised form 22 April 2009
Accepted 22 April 2009
Available online xxxx
Editor: T.M. HarrisonG. Av? Lallemant c, Virginia B. Sisson d, George E. Harlow e,
ns f, Tatsuki Tsujimori g, Sorena S. Sorensen h
lege and The Graduate Center, CUNY, Flushing, NY 11367, USA
y, Palisades, NY 10964, USA
X, 77005, USA
n, TX, 77204, USA
Museum of Natural History, New York, NY 10024, USA
tanford University; Stanford, CA 94305, USA
d Cosmochemistry, Institute for Study of the Earth's Interior, Okayama University, Misasa, Tottori 682-0193, Japan
atural History, Smithsonian Institution, Washington, DC 20560, USA
a b s t r a c t
The Guatemala suture zone is a major east?west left-lateral strike slip boundary that separates the North
American and Caribbean plates in Guatemala. The Motagua fault, the central active strand of the suture zone,
underwent two major collisional events within a system otherwise dominated by strike?slip motion. The ?rst
event is recorded by high-pressure/low temperature (HP/LT) eclogites and related rocks that occur within
serpentinites both north and south of the Motagua fault. Lawsonite eclogites south of the fault are not
signi?cantly retrograded and give 40Ar/39Ar ages of 125?116Ma and Sm?Ndmineral isochrons of 144?132Ma.transpressional tecton
Motagua fault, Guatemala: A record of Neocomian and Maastrichtian
Metamorphic reworking of a high pressu
j ourna l homepage: wwws were interpreted origi-
two tectonostratigraphic
nd to re?ect the closure
ervatory, Columbia University,
eckner).
ll rights reserved.
et al., Metamorphic reworkin
nd Maastrichtian..., Earth Pla?low temperature m?lange along the
y Science Letters
l sev ie r.com/ locate /eps lmany modern compressional terrane boundaries are not perpendic-
ular to convergent directions, but oblique and so older serpentinite
belts may also re?ect oblique convergence at the time they formed.
We propose that two HP/LT bearing serpentinite belts that occur
parallel to each other across the Motagua fault in Guatemala, Central
America are examples of a suture that evolved through oblique con-
vergence. 40Ar/39Ar ages from HP/LT rocks within the serpentinites
(Harlow et al., 2004) give Early Cretaceous age south of the fault
g of a high pressure?low temperature m?lange along the Motagua
net. Sci. Lett. (2009), doi:10.1016/j.epsl.2009.04.032
and Late Cretaceous age north of the fault, which indicate that the
exposed serpentinites were juxtaposed by strike slip movement along
the Motagua fault. Here we present Sm?Nd geochronology from
eclogites that show the original recrystallization of the eclogites on
both sides occurred at the same time during the Early Cretaceous,
which indicates that the two belts shared an early history of con-
vergence and subduction. A common early history, but a different
subsequent history involving both large magnitude strike slip and dip
slip movement suggests that the Motagua fault is part of a boundary
that has undergone oblique convergence since the early Cretaceous.
2. Regional setting
The Guatemala suture zone is presently part of a major left lateral
strike slip boundary between the North American plate to the north
(locally known as the Maya block) and Caribbean plate (locally, the
Chort?s block) to the south (Fig. 1). The present displacement rate
along the Guatemala suture zone is estimated at about 21 mm/year
(DeMets et al., 2007) and the total displacement since the Early
Eocene is estimated to be ?1100 km (Rosencrantz and Mann, 1991).
The three major strands of the Guatemala suture zone are, from north
to south, the Poloch?c, Motagua, and Jocot?n faults. The Motagua fault
(a.k.a. San Agust?n?Motagua?Caba?as?Jubuco and Cuyamel faults)
and granitoids south of the fault are sparse and so cannot be compared
with those to the north.
Major faults associated with the Motagua fault are shown in Fig. 1.
They are ENE?WSW trending north-vergent thrust faults in the north,
south-vergent thrust faults in the south, and steeply dipping strike
slip faults in themiddle. Mesoscopic structures are generally related to
motions along the large faults. Kinematic indicators in metamorphic
rocks, both north and south of the Motagua fault, indicate left-lateral
strike slip and dip slip movement. The very strong stretching lineation
in these rocks is subhorizontal and EW-trending indicating consider-
able lateral displacement. A less developed NS-trending lineation indi-
cates some strain or displacement occurred to the north and/or south
(Francis, 2005; Francis et al., submitted for publication), consistent with
the presence of thrust faults and eclogite-facies rocks. 40Ar/39Ar dates
indicate these displacements occurred throughout the Cretaceous
(Harlow et al., 2004). NE and NW striking high angle faults within the
Motagua Valley are related to the generation of pull-apart basin ?lled
with Tertiary sediments and indicate that movement since the Late
Cretaceous was largely strike slip. Late high angle normal faults occur in
the mountains on both sides of the Motagua fault that dip steeply
towards the Motagua valley with downward dip slip motion of the
blocks closest to the river. These faults are probably related to the uplift
of mountain ranges on both sides of the fault.
ajo
(C)
h?c,
2 H.K. Brueckner et al. / Earth and Planetary Science Letters xxx (2009) xxx?xxx
ARTICLE IN PRESSruns ENE?WSW more or less along the Motagua River and is
sometimes considered the actual present-day boundary between
the Maya block and the Chort?s block (however, see Ortega-Guti?rez
et al., 2007 for a more complex interpretation of the boundary).
Lithologic units on opposite sides are, with the exception of
serpentinites and related rocks, quite different (Martens et al.,
2007a,b), consistent with considerable lateral displacement along
the Motagua fault. The units in the Maya block include the Chuac?s
metamorphic complex, recently shown to include eclogitic lenses that
record a Late Cretaceous HP/HT event (Ortega-Guti?rrez et al., 2004,
Martens et al., 2007b, 2009), Paleozoic sedimentary rocks of the Santa
Rosa Group, low-grade metasediments (white mica?chlorite schists,
quartzite, andminormarble) associatedwithantigorite schist/m?lange
and deformed granites. The Chort?s block contains the greenschist-facies
San Diego phyllite, the amphibolite-facies Las Ovejas complex, and
relatively undeformed granitoids. Numerous U?Pb zircon ages from
granites and their host gneisses north of the fault give Late Proterozoic
(Grenville), Carboniferous, and Triassic ages as well as a metamorphic
event at ca. 70 Ma (Martens et al., 2007a,b, 2009). Ages from gneisses
Fig. 1. Generalized map of the Motagua Valley of Guatemala showing distribution of m
localities from Carrizal Grande (A), R?o Belejey? (B), and Quebrada de los Pescaditos
northwestern Caribbean and location of the study area (rectangle). Faults are P ? PolocPlease cite this article as: Brueckner, H.K., et al., Metamorphic reworkin
fault, Guatemala: A record of Neocomian and Maastrichtian..., Earth PlaSerpentinite bodies and serpentinite m?langes occur throughout
the Guatemala suture zone (see inset in Fig. 1). However the antigorite
serpentinites that contain HP/LT eclogites, jadeitites and other unusual
rocks appear to be restricted to both sides of theMotagua fault (Harlow
et al., 2003, 2004; Tsujimori et al., 2006a,b; Sorensen et al., 2006). The
distribution of these eclogite-bearing serpentinites along the Motagua
fault (Fig. 1) seems to create a dilemma since the apparent offset be-
tween the two sides based on surface exposure could range from 0 to, at
most, 80 km(20kmaccording toDonnellyet al.,1990). The serpentinites
should have been displaced laterally bymuch larger distances relative to
each other if theMotagua fault is amajor active strand of the Guatemala
strike slip system. Harlow et al. (2004) addressed the apparent lack of
offset by proposing that the eclogite bearing serpentinites, though super-
?cially similar, are of different age and originated more than 1000 km
apart and thenwere juxtaposed by strike slip motion along the Motagua
suture zone. This coincidental juxtaposition seemed tenable because
Ar?Ar ages from phengite and other phases were different on the two
sides: ca. 60 Ma to the north and ca. 125 Ma to the south. Juxtaposition
of HP/LT terranes that formed at different times seemed reasonable.
r strike slip faults, thrust faults (lines with barbs), serpentinites, and eclogite sample
. Adapted from Francis et al. (submitted for publication). Inset: Tectonic map of the
M ? Motagua, and J ? Jocot?n. Together they comprise the Guatemala suture zone.g of a high pressure?low temperature m?lange along the Motagua
net. Sci. Lett. (2009), doi:10.1016/j.epsl.2009.04.032
3H.K. Brueckner et al. / Earth and Planetary Science Letters xxx (2009) xxx?xxx
ARTICLE IN PRESSHowever the results that will be presented below indicate that both
suites of HP/LT rocks formed at the same time and so the juxtaposition
model would require that two HP/LT terranes of identical age were
juxtaposed by large-scale strike slip displacements.We propose a geom-
etry that can explain this apparent conundrum further along in this
manuscript.
3. Serpentinites
All serpentinites and serpentinite m?langes are tectonic slices
bounded by thrust faults or by steep E?W strike slip faults (Francis,
2005). The thrust faults have been interpreted as ??ower structures?
(Beccaluva et al., 1995; Giunta et al., 2002), but the cross-cutting strike
slip faults and dip slip faults discussed above suggest that they are not
contemporaneous with Tertiary strike slip motion along the Motagua
ault (McBirney, 1963; McBirney et al., 1967; Donnelly et al., 1990;
Francis, 2005; Tsujimori et al., 2006a; Francis et al., submitted for
publication). The serpentinites that contain HP/LT blocks occur
immediately north and south of the Motagua fault are antigorite
dominant and heavily sheared. Antigorite serpentinites south of the
fault are associated with low-grade siliciclastic rocks and minor basalt
(including pillow basalt) and are considered components of the El
Tambor complex. Radiolaria from cherts within the El Tambor have a
Late Jurassic age (Chiari et al., 2002). The antigorite serpentinites north
of the Motagua fault are presumably of similar age, but their relation-
ship to the El Tambor complex is less clear. Lower temperature
chrysotile?lizardite-bearing serpentinites occur over a wider area in
the Guatemala suture zone ranging from selvages in the El Tambor
formation just south of theMotagua fault to the Juan de Paz serpentinite
(Muller, 1979) just north of the Motagua fault and the extensive Santa
Cruz and Baja Verapaz ultrama?c complexes further north of the
Motagua fault. These serpentinites contain no HP/LT blocks though
some contain some amphibolites. They are assigned an Early Cretaceous
age based on fossils from the Santa Cruz serpentinites (Rosenfeld,
1981). It appears that low temperature serpentinites and associated
ophiolitic rocks north of the Motagua fault, particularly those adjacent
to the Poloch?c fault, are younger (Early Cretaceous) than the antigorite
serpentinites of the El Tambor in the immediate vicinity of the fault
(Late Jurassic).
4. Eclogites and associated rocks
Eclogite sample localities are shown in Fig. 1. Eclogites, jadeitites,
albitites, andotherHP/LTrocks areusually foundasboulders in the rivers
that drain antigorite-bearing serpentinite bodies (Fig. 1) and ?ow into
the Motagua River. Eclogites south of the Motagua fault were collected
from river drainages below the village of Carrizal Grande. Eclogite north
of the Motagua fault were collected along Quebrada de Los Pescaditos
about 5 km south of San Buenaventura and from R?o Belejey? about
5 km west of Granados. Detailed petrography of these samples is pre-
sented in Appendix A or for samples ACG-01 and ACG-17, by Tsujimori
et al. (2006a,b).
Trace and major element geochemistry and Li, Sr, and Nd isotopic
patterns of eclogites, peridotites, serpentinites, and jadeitites
indicate that the eclogite protoliths from both sides of the fault
originated at a mid-ocean ridge and subsequently were metamor-
phosed and metasomatized in a mantle wedge above a subduction
zone (Beccaluva et al., 1995; Sorensen et al., 2006; Simons et al.,
submitted for publication). Petrographic and thermobarometric
studies of the eclogite mineral assemblages indicate they are of the
?blueschist? or ?Franciscan? type, typical of subduction complexes
(Ernst, 1988). Eclogites south of the Motagua fault range from
pristine to mildly retrograded. They contain garnet+omphacite
(?jadeite)+lawsonite (several generations)+rutile?quartz?
phengite?apatite?titanite?chlorite?sul?de and show prograde
metamorphic textures. P?T equilibration conditions are estimated at
Please cite this article as: Brueckner, H.K., et al., Metamorphic reworkin
fault, Guatemala: A record of Neocomian and Maastrichtian..., Earth Pla300?480 ?C and 1.1 to 2.6 GPa (Tsujimori et al., 2006a). Retrograde
features, where developed, occur as reversely zoned garnet rims
associated with secondary omphacite+lawsonite+titanite?phen-
gite?glaucophane?albite+quartz?apatite?sul?de assemblages
estimated to have formed at P?1.4 GPa and T?400 ?C (Tsujimori
et al., 2005, 2006a). An even younger blueschist overprint consists of
glaucophane+lawsonite+chlorite+titanite+quartz?phengite. Tsu-
jimori et al. (2006a) estimate that the P?T trajectory of these assem-
blages lies along a geotherm of ?5 ?C/km, comparable to the coldest
geotherms from subduction zones worldwide.
The metabasites north of the Motagua fault zone are mostly garnet
amphibolites that contain clinozoisite and pargasite/magnesio-horn-
blende amphibole with rare omphacite and abundant clinozoisite and
amphibole inclusions in garnet. The rare omphacite inclusions suggest
initial eclogite-facies crystallization. The clinozoisite and amphibole
inclusions suggest a later high pressure amphibolite facies metamor-
phism with a garnet crystallization temperature of 500?600 ?C at a
pressure of ~1.2?1.5 GPa (Harlow et al., 2008). An even later assemblage
of clinozoisite+albite+quartz+actinolitic amphibole indicates a sub-
sequent greenschist overprint. True eclogite was found by us recently in
the western reaches of the m?lange zone north of the Motagua fault
(Fig.1) though theycontainprimary clinozoisite instead of lawsonite. The
primary assemblage of garnet+omphacite, +phengitic muscovite+
rutile+clinozoisite, +glaucophanic to pargasitic amphibole?quartz
suggests a higher temperature (500?600 ?C) of formation than the
southern eclogites. This eclogite assemblage is moderately to strongly
overprinted by a clinozoisite+actinolitic amphibole?paragonite?
biotite+titanite+albite+quartz?apatite?sul?des assemblage sug-
gesting subsequent recrystallization at comparable temperatures
(T?550?600 ?C, Tsujimori et al., 2004; Harlow et al., 2008). The
secondary assemblages were initially interpreted as retrograde assem-
blages formed during decreasing pressure and temperature conditions
(Harlowet al., 2004), but are nowbelieved to have formed during a later
metamorphism. Thus the northern eclogites underwent a later greens-
chist to amphibolite facies recrystallization event whereas the southern
eclogites did not. These distinct P?T histories are supported by 40Ar/39Ar
phengite and/or amphibole dateswith southern eclogites giving ages of
125?116 Ma while northern eclogites and associated rocks give ages of
88?55 Ma (Harlow et al., 2004).
5. Results
Sm?Nd analytical procedures are described in Appendix B and the
data are presented and discussed in detail in Appendix C. Six of the
most meaningful results (out of eight samples analyzed) are plotted
on Fig. 2. The Sm?Nd ages considered reliable have low error (low
MSWD), contain more than one garnet analysis, or an analysis of an
additional phase besides garnet and clinopyroxene (i.e., phengite,
apatite). The most precise ages from south of the Motagua fault are
the 132.1?6.5 Ma age from MVE02-6-3 (Fig. 2A) and the 143.9?
9 Ma from ACG-03 (Fig. 2B). The latter age becomes 140.6?3.4 Ma
(MSWD=0.54) if the ?rst garnet analysis (64 ratios, low intensity) is
excluded. This age is considered relatively robust, despite the lack of a
whole rock analysis because three phases were analyzed. The results
from sample MVE02-14-6 are more equivocal. Five garnet separates
were analyzed with each analysis plotting at a different location
(Fig. 2C). The resultant scatterchron (MSWD=83) age of 133?14Ma
is obviously an average. The ?nal two garnet analyses attempted to
separate and date the darker garnet core from the lighter rim by color.
However the pink rim (+2 clinopyroxenes and 2 whole rock
samples) gives an older age (130.2?1.6 Ma) than the redder core
(123.8?1.9 Ma) and the oldest age is obtained from the second
analysis of a bulk garnet sample (144.7?1.6 Ma). The scattered ages
are provisionally interpreted as re?ecting the span of garnet growth,
suggesting this growth began at ca.145Ma and ended roughly twenty
million years later at ca. 124 Ma.
g of a high pressure?low temperature m?lange along the Motagua
net. Sci. Lett. (2009), doi:10.1016/j.epsl.2009.04.032
4 H.K. Brueckner et al. / Earth and Planetary Science Letters xxx (2009) xxx?xxx
ARTICLE IN PRESSThe ages considered reliable from north of the fault are from two
relatively weakly overprinted eclogites. They are 130.7?6.3 Ma from
MVE04-44-7 from Quebrada de Los Pescaditos (Fig. 2D) and the
125.0?7.8 Ma age from MVE06-5-3 from R?o Belejey? (Fig. 2E). The
125.0?7.8 Ma (MSWD=1.3) age from R?o Belejey? (Fig. 2E) is
considered particularly robust. Analysis of the quartz- and albite-
rich fraction yielded a point that occupies an intermediate position
on the mineral isochron diagram, something that is rare in eclogite
analyses and gives con?dence in the isochron. The fraction probably
contained hydroxylapatite based on its abundance in thin section
(Appendix A).
Sample MVE04-44-6 from Quebrada de Los Pescaditos generated
an age of 166?22Ma (Fig. 2F). The scatter (MSWD=6.6) is produced
by the positions of two clinopyroxenes above and two whole rocks
below the best-?t line. We suspect ?uid-introduced crustal Nd
lowered the 143Nd/144Nd ratios of the whole rock and, to a lesser
extent, the clinopyroxenes, thereby producing scatter and steepening
of the best-?t line to produce an unrealistic old age.
The four most credible ages are essentially Early Cretaceous
(Neocomian) and give an average of 132 Ma and a weighted average of
136?11 Ma. However, all ages probably ?average? a period of eclogite-
facies recrystallization that, based on the age span for garnets from
MVE02-14-6 (Fig. 2C), may have lasted 20 million years or more. The
ages appropriately post-date the formation of the youngest ocean ?oor
lithology found south of the Motagua fault, the Late Jurassic El Tambor
ophiolite (Chiari et al., 2002), suggesting similar age crust was subducted
to form the eclogites. The Sm?Nd ages are also consistent with the
40Ar/39Ar ages of 116?125 Ma determined from the southern eclogites,
but are much older that the 40Ar/39Ar ages of 88?55 Ma from eclogites
and related rocks north of the fault (Harlow et al., 2004).
Fig. 2. Sm?Nd mineral isochron plots of eclogites from the Carrizal Grande, Chort?s block (A,B
details are presented in Appendix B.
Please cite this article as: Brueckner, H.K., et al., Metamorphic reworkin
fault, Guatemala: A record of Neocomian and Maastrichtian..., Earth Pla6. Discussion
6.1. An apparent conundrum resolved
The Motagua fault is active today based on offset terraces and
the 1976 magnitude 7.5 earthquake (Schwartz et al., 1979). Never-
theless, Donnelly et al. (1990) estimated the total displacement along
the Motagua fault as only 20 km appearing to create a conundrum of
why large scale strike slip motion along the Guatemala suture zone
(?1100 km according to Rosencrantz and Mann, 1991) did not send
these HP/LT rocks hundreds of kilometers in opposite directions. The
solutionmay be that theMotagua fault became the active strand of the
Guatemala suture zone relatively recently, consistent with recent plate
tectonic reconstructions that show the Motagua fault was not active
until the Early Pliocene, 4 Ma ago, and that most of the Post-Cretaceous
motion along the present Guatemala suture zone was carried by the
Poloch?c and Jocot?n Faults (Rogers and Mann, 2007). If the estimated
?21 mm/yr displacement rate of the Guatemala suture zone occurred
solely along the Motagua fault for only the last 4 Ma, the total dis-
placement of ?84 km is greater than the apparent displacement of
20 kmestimatedbyDonnelly et al. (1990), butwithin the displacements
inferred from the outcrop distribution in Fig. 1.
However, as already noted, stretching lineations in mylonites are
parallel to the Motagua fault suggesting signi?cant long-term left-
lateral displacement under metamorphic conditions (McBirney, 1963;
McBirney et al., 1967; Donnelly et al., 1990; Francis, 2005; Tsujimori
et al., 2006a,b; Francis et al., submitted for publication). In addition, the
Motagua fault is associated with trans-extensional basins containing
the Eocene or older beds of the Subinal Formation suggesting left-lateral
movement for at least 30?40 Ma. The most important observation,
,C) and from Quebrada los Pescaditos (D,F) and Rio Belejey? (E), Maya block. Analytical
g of a high pressure?low temperature m?lange along the Motagua
net. Sci. Lett. (2009), doi:10.1016/j.epsl.2009.04.032
5H.K. Brueckner et al. / Earth and Planetary Science Letters xxx (2009) xxx?xxx
ARTICLE IN PRESShowever, is that the P?T-t histories of the eclogites on opposite sides of
the fault are signi?cantly different, despite forming initiallymore or less
at the same time. The lower Cretaceous history differs in that the
southern eclogites record lawsonite eclogite formation along a very cold
subduction trajectory (~5 ?C/km)whereas thenorthern eclogites record
a warmer lawsonite-free trajectory (~7 ?C/km). But the most striking
difference is the ca. 70 Ma greenschist/amphibolite-facies overprint
recorded by the northern eclogites, but not the southern eclogites.
These observations argue that eclogites from different initial locations
were indeed juxtaposed by large-scale strike slip motion as originally
suggested by Harlow et al. (2004). But the question remains as to why
HP/LT terranes, initially far apart and with different histories, would
have a common Early Cretaceous origin.
This dilemma is resolved if the Guatemala suture zone, and the
Motagua fault in particular, follow a Lower Cretaceous convergent
suture for a large portion of its length. The implication of this geometry
is that eclogite-bearing serpentinites could occur at depth along much
of the suture zone, but the terranes on opposite sides would have
undergone different histories as a result of different initial positions in
the suture followed by large lateral displacements. This geometry is
not unique. For example, Cordilleran terranes, including convergent
system such as the Franciscan Formation, underwent large-scale strike
slip displacements (1000?3000 km) parallel to the western margin of
North America throughout Late Jurassic, Cretaceous and Tertiary time
(e.g., Av? Lallemant andOldow,1988; Umhoefer andDorsey,1997). Thus
the terranes on opposite sides of the Motagua fault could have been
originally from the sameLower Cretaceous subduction system, butwere
positioned far apart along strike in areas where one terrane underwent
a subsequent Late Cretaceous event whereas the other did not.
6.2. Recent exhumation
An additional consequence of this geometry is that HP/LT ter-
ranes could be exposed on either side or both sides of the fault at any
time at any place along the length of the Motagua fault given the
operation of a suitable exhumation mechanism. The serpentinites and
serpentinite m?langes shown on Fig. 1 occur amidst two ranges; the
Sierra de Las Minas range to the north, uplifted to about 3000 m above
theMotaguaValleyandanunnamed range to the south that is uplifted to
an average of 1500 m above the Motagua Valley (Edwards et al., 2000;
Rogers et al., 2002). Both ranges are undergoing active uplift today as a
result of transpression along the Motagua fault (Rogers et al., 2002),
which shows a change in trend from ENE?WSW in the east to E?W in
the area of the mountain ranges (Fig. 1). Fission track dating suggests
these ranges began uplift between 55?31 and 24?16 Ma ago for the
northern and southern ranges respectively (Francis, 2005). The
exposure of the serpentinites and their cargo of HP/LT rocks is thus a
recent and spatially restricted phenomenon caused by the local exis-
tence of a restraining bend. Their recent exhumation on both sides of
the fault explains their apparent lack of large-scale displacement along
a fault system that has undergonemajor strike slip motion. Presumably
continued strike slip motion on the Motagua fault will send the two
LT/HP terranes in opposite directions and create a signi?cant offset well
into the future. If our suggestion is correct, similar eclogite-bearing
antigorite serpentinitesmay occur alongmuch of theMotagua fault, but
are still at depth awaiting an exhumation mechanism.
6.3. A strike slip/convergent tectonic model
There is strong evidence that the Chort?s block originated from
the west coast of Mexico and was translated towards the southeast
along left lateral strike slip faults (Pindell, 1994; Mann, 2007; Pindell
and Kennan, in press). Yet, the presence andmetamorphic ages of HP/
LT eclogites within serpentinites of the Motagua fault require two
convergent events as well; Early Cretaceous subduction of the Paleo-
Paci?c beneath western Mexico followed roughly 60 my later by a
Please cite this article as: Brueckner, H.K., et al., Metamorphic reworkin
fault, Guatemala: A record of Neocomian and Maastrichtian..., Earth Placollision of the Maya block with another terrane. Thus, any tectonic
model for the evolution of these rocks requires synchronous or
alternating strike slip motion and convergence. We propose a
synchronous model where oblique convergence of the Farallon plate
with western Mexico resulted in the formation of both a left-lateral
strike slip system (the Paleo-Motagua fault zone) parallel to the plate
boundary and a spatially coincident subduction system with motion
normal to the plate boundary (Fitch, 1972; Av? Lallemant and Guth,
1990). Thus the event that initially crystallized theHP/LTeclogites of the
Motagua fault (Fig. 3A) during the Early Cretaceous involved the
subduction of the Farallon plate beneath western Mexico, as shown in
Fig. 3A, or possibly a terrane outboard of Mexico. A discrete collision
between the Chort?s block and western Mexico is not required and
portions of the Farallon oceanic crust may have survived locally along
strike. The Upper Jurassic El Tambor ophiolite complex represents
obducted fragments of the Farallon plate, whereas the HP/LT eclogites
represent deeply subducted fragments of the Farallon plate that
underwent metamorphism typical of ?Franciscan?-type eclogites as
theymixedwith serpentinites created by the aqueousmetasomatism of
the mantle wedge above the subduction zone (Fig. 3A). The different
Early Cretaceous P?Tgradients of the northern versus southern eclogites
suggest that they were generated in different places within the
subduction complex and therefore underwent different P?T trajectories
(Gerya et al., 2002; Gorczyk et al., 2007). A subduction complex can be
active for many tens of millions of years explaining, the N20 million year
interval of eclogite growth inferred from some of the Sm?Nd dates
presented in Fig. 2. The P?T and chemical history within an accretionary
prism can be quite complex as the eclogite protoliths are churned to
different levels below the mantle wedge and as ?uids of different
compositions ?ux through at different times (Krebs et al., 2008).
A portion of this accretionary prism, with its cargo of serpentinites,
eclogites, and other HP rocks, was thrust over the leading edge of the
Chort?s block (Fig. 3A) and isolated from subsequent convergent
tectonics. The northward dip of thrust faults on the Chort?s block is
consistent with this model (Fig. 1). The apparent paucity of deep sea
lithologies normally associated with accretionary prisms may require
a system relatively starved of sediments, similar to those that occur
today west of the Andes of South America. Alternatively, much of the
accretionary prism may have been subducted (e.g., von Huene et al.,
2004; Scholl and von Huene, 2007).
Subsequently, new oceanic crust was generated between the Chort?s
block and western Mexico as a result of rotation and left lateral trans-
lation along the Paleo-Motagua fault zone forming, in effect, a trans-
extensional marginal basin that widened for much of the Cretaceous
(Francis, 2005). The existence of a basin that ?oored by younger crust is
supported by the Early Cretaceous fossils found within the Santa Cruz
and Juan de Paz ophiolites (Muller, 1979; Rosenfeld, 1981) north of the
Motagua fault. This new crust may or may not have been bordered by
remnants of the older Farrallonplate. The evolution of this ocean system
changed from spreading to contraction some time before the end of the
Cretaceous culminating in the oblique collision at ca. 70 Ma of the
southern end (present coordinates) of theMayablockorperhapsa sliver
of this block, now called the Chuac?s complex, with a southern terrane
that presently has moved well to east of the position that Chort?s block
presently occupies across the Motagua fault. This shifted terrane
presumably is now part of the Nicaraguan Rise or the Great Antilles
Arc (Martens et al., 2009).
The second oblique collision is given substantial credibility by
recently discovered HP/HT crustal eclogites within the crystalline
Chuac?s complex of the Maya block (Ortega-Guti?rrez et al., 2004;
Martens et al., 2007a,b, 2009) indicating the Chuac?s complex was
subducted 60 km into the mantle in an Himalayan style collision. The
age of this crustal-subduction event is dated at 65 to 70 Ma based on
U?Pb zircon ages from Chuac?s gneisses (Martens et al., 2007a,b), a
68?8 Ma U?Pb age from a zircon rim within eclogite (Martens et al.,
2008) and a ca. 76 Ma Sm?Nd mineral isochron from an eclogite
g of a high pressure?low temperature m?lange along the Motagua
net. Sci. Lett. (2009), doi:10.1016/j.epsl.2009.04.032
6 H.K. Brueckner et al. / Earth and Planetary Science Letters xxx (2009) xxx?xxx
ARTICLE IN PRESS(Martens et al., 2009). These ages overlap the Ar?Ar ages of 88?55 Ma
from eclogites within the northern block serpentinites. It seems
inescapable that the synchronous subduction of the Chuac?s, the
formation of HP/HT eclogites within the Chuac?s, and the thermal
event that reset Ar?Ar ages and retrograded the HP/LT assemblages
within serpentinites north of the fault were linked. We suggest that
fragments of the Mid to Late Cretaceous sea?oor (i.e., the Santa Cruz,
Juan de Paz, and Baja Vera Paz ophiolites) of the basin that had
separated the Chort?s andMaya blocks as well as fragments of whatever
portions remained of the Farallon plate were obducted onto the Maya
block as the Chuac?s complex began to underthrust the southern block
(Fig. 3B). The southward dip of thrust faults north of the Motagua fault
is consistent with this model. The leading edge of the eclogite-bearing
Lower Cretaceous accretionary prism was obducted as well. As con-
vergence continued another portion of the Lower Cretaceous HP/LT
serpentinite m?lange assemblages was re-subducted resulting in the
greenschist/amphibolite facies re-metamorphismof theHP/LTeclogites
at ca. 70 Ma (Fig. 3B) while the underlying Chuac?s complex subducted
to even deeper levels to form HP/HT eclogites.
7. Conclusions
High pressure/low temperature (HP/LT) eclogites within antigorite-
bearing serpentinite crop out north and south of the Motagua fault, a
major strand of the Guatemala suture zone that forms the boundary
between the North American and Caribbean plates. The northern asso-
ciation differs from the southern association in petrography, P?T condi-
tions of formation, degree of retrogression, and 40Ar/39Ar ages.However,
Fig. 3. Cartoon showing possible mechanisms for the evolution of Guatemala HP/LT eclogit
generated eclogites. A. Exhumation of serpentinites within an accretionary wedge during su
crust and serpentinizedmantle detach from the subducting lithosphere and the hanging wall
Cretaceous ocean basin thrust theMaya block beneath a southern terrane, possiblywhat is no
pressure re-metamorphism of the accretionary prism and high pressuremetamorphism of th
and its cargo of obducted eclogite-hosting serpentinites at Carrizal Grande was juxtaposed a
large scaled strike slip motion along the Paleo-Motagua fault zone and, later, along the Mot
Please cite this article as: Brueckner, H.K., et al., Metamorphic reworkin
fault, Guatemala: A record of Neocomian and Maastrichtian..., Earth PlaSm?Nd mineral isochrons from eclogites show that the initial meta-
morphism that created the eclogites in both terranes occurred at the
same time, at ca. 140?120 Ma, probably within the same accretionary
system. The Early Cretaceous exhumation of the HP/LT eclogites and
associated rocks south of the Motagua fault caused them to be largely
unaffected by later events. Those north of the fault, however, were
subjected to a subsequent oblique collision at ~70 Ma. The disparity
between P?T-t records on opposite sides of the fault suggest that the two
terranes were separated from each other by a signi?cant lateral distance
along the Motagua fault during the Late Cretaceous collision. Their
present juxtaposition across a strike slip system means that their
positioning occurred since the last oblique collision at ~70 Ma. It was
most likely produced by left-lateral displacement of the present Chort?s
block, with its Lower Cretaceous collisional remnants, to its current
position adjacent to the Chuac?s, although the amount of displace-
ment is unknown. The apparent lack of strike slip displacement based
on present surface exposure is therefore deceptive. Serpentinite hosting
HP/LT rocks probably occur at depth along much of the modern
Guatemala suture zone, but with different P?T-t histories on opposite
sides of the Motagua fault. The two presently exposed terranes were
exhumed opposite each other by recent uplift resulting from strike slip
motion along a restraining bend. Thus the two terraneswere juxtaposed
at depth by large-scale strike slip motion along the Motagua fault, but
their exposure across the fault is due to recent vertical movement and
erosion. In summary, our data show that what appears to be a simple
terrane boundary de?ned by serpentinites with HP/LT blocks is not a
record of simple continental accretion but rather amore complex record
of metamorphic reworking during two oblique collisional events as a
es through transpressional tectonics. The diagrams emphasize the dip slip motion that
bduction of the Paleo-Paci?c beneath Mexico between 144?125 Ma. Eclogitized oceanic
and are thrust over the Chort?s block. B. Closure of the remnant ocean and newly formed
w the Nicaragua Rise or the Great Antilles Arc (Martens et al., 2009) resulting inmedium
e more deeply subducted Chuac?s complex at ca. 70Ma. Subsequently the Chort?s block
cross the Motagua fault with the Maya Block and its cargo of northern serpentinites by
agua fault.
g of a high pressure?low temperature m?lange along the Motagua
net. Sci. Lett. (2009), doi:10.1016/j.epsl.2009.04.032
7H.K. Brueckner et al. / Earth and Planetary Science Letters xxx (2009) xxx?xxx
ARTICLE IN PRESSresult of the oblique convergence of the Farallon and North American
plates.
The HP/LTmetamorphic rocks in the Guatemala suture zone are like
beads in a bracelet; they are not only displaced over great distances, but
they are also stretched. Rocks similar to the Guatemalan HP/LT rocks
occur throughout the Caribbean?North American plate boundary; and
can be found eastward to Cuba and the Dominican Republic. The east?
west trending southern Caribbean South American plate boundary is
similarly decorated with HP/LT rocks; they have been found from
Margarita Island (Venezuela) to Colombia. The oblique evolutionmodel
described here for eastern Guatemala appears to be a ubiquitous feature
of these two major strike slip terrane boundaries and may apply to
similar systems worldwide.
Acknowledgements
This work was funded by NSF Grants EAR 0309832 to SRH and HKB,
EAR0309320 to GEH, and EAR0309116 to HGAL. This project is part of
IGCP Project 546 on ?Subduction Zones of the Caribbean.? We thank
Carlos Gonzales for ?eld assistance. We appreciate constructive reviews
by Jim Pindell, Sarah Roeske, Taras Gerya, Bradley Hacker and an
anonymous reviewer. This contribution is publication number 7265 of
Lamont?Doherty Earth Observatory.
Appendix A. Supplementary data
Supplementary data associated with this article can be found, in
the online version, at doi:10.1016/j.epsl.2009.04.032.
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fault, Guatemala: A record of Neocomian and Maastrichtian..., Earth Plag of a high pressure?low temperature m?lange along the Motagua
net. Sci. Lett. (2009), doi:10.1016/j.epsl.2009.04.032