Spirit Mars Rover Mission to the Columbia Hills, Gusev Crater: Mission overview and selected results from the Cumberland Ridge to Home Plate R. E. Arvidson,1 S. W. Ruff,2 R. V. Morris,3 D. W. Ming,3 L. S. Crumpler,4 A. S. Yen,5 S. W. Squyres,6 R. J. Sullivan,6 J. F. Bell III,6 N. A. Cabrol,7 B. C. Clark,8 W. H. Farrand,9 R. Gellert,10 R. Greenberger,1 J. A. Grant,11 E. A. Guinness,1 K. E. Herkenhoff,12 J. A. Hurowitz,5 J. R. Johnson,12 G. Klingelho?fer,13 K. W. Lewis,14 R. Li,15 T. J. McCoy,16 J. Moersch,17 H. Y. McSween,17 S. L. Murchie,18 M. Schmidt,15 C. Schro?der,3 A. Wang,1 S. Wiseman,1 M. B. Madsen,19 W. Goetz,20 and S. M. McLennan21 Received 12 May 2008; revised 1 July 2008; accepted 31 July 2008; published 6 November 2008. [1] This paper summarizes the Spirit rover operations in the Columbia Hills of Gusev Crater from sols 513 to 1476 and provides an overview of selected findings that focus on synergistic use of the Athena Payload and comparisons to orbital data. Results include discovery of outcrops (Voltaire) on Husband Hill that are interpreted to be altered impact melt deposits that incorporated local materials during emplacement. Evidence for extensive volcanic activity and aqueous alteration in the Inner Basin is also detailed, including discovery and characterization of accretionary lapilli and formation of sulfate, silica, and hematite-rich deposits. Use of Spirit?s data to understand the range of spectral signatures observed over the Columbia Hills by the Mars Reconnaissance Orbiter?s Compact Reconnaissance Imaging Spectrometer (CRISM) hyperspectral imager (0.4?4 mm) is summarized. We show that CRISM spectra are controlled by the proportion of ferric-rich dust to ferrous-bearing igneous minerals exposed in ripples and other wind- blown deposits. The evidence for aqueous alteration derived from Spirit?s data is associated with outcrops that are too small to be detected from orbital observations or with materials exposed from the shallow subsurface during rover activities. Although orbital observations show many other locations on Mars with evidence for minerals formed or altered in an aqueous environment, Spirit?s data imply that the older crust of Mars has been altered even more extensively than evident from orbital data. This result greatly increases the potential that the surface or shallow subsurface was once a habitable regime. Citation: Arvidson, R. E., et al. (2008), Spirit Mars Rover Mission to the Columbia Hills, Gusev Crater: Mission overview and selected results from the Cumberland Ridge to Home Plate, J. Geophys. Res., 113, E12S33, doi:10.1029/2008JE003183. 1. Introduction [2] The Mars Exploration Rover, Spirit, touched down on the volcanic plains of Gusev Crater on 4 January 2004. During its first 156 sols Spirit conducted traverses and made measurements on the olivine-bearing basaltic plains that JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 113, E12S33, doi:10.1029/2008JE003183, 2008 Click Here for Full Article 1Department of Earth and Planetary Sciences, Washington University, St. Louis, Missouri, USA. 2School of Earth and Space Exploration, Arizona State University, Tempe, Arizona, USA. 3Johnson Space Center, NASA, Houston, Texas, USA. 4New Mexico Museum of Natural History and Science, Albuquerque, New Mexico, USA. 5Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA. 6Department of Astronomy, Cornell University, Ithaca, New York, USA. 7NASA Ames/SETI Institute, Moffett Field, California, USA. 8Lockheed Martin Corporation, Littleton, Colorado, USA. 9Space Science Institute, Boulder, Colorado, USA. 10Department of Physics, University of Guelph, Guelph, Ontario, Canada. Copyright 2008 by the American Geophysical Union. 0148-0227/08/2008JE003183$09.00 E12S33 11Center for Earth and Planetary Studies, National Air and Space Museum, Smithsonian Institution, Washington, District of Columbia, USA. 12U. S. Geological Survey, Flagstaff, Arizona, USA. 13Institut fu?r Anorganische und Analytische Chemie, Johannes Gutenberg- Universita?t, Mainz, Germany. 14California Institute of Technology, Pasadena, California, USA. 15Department of Civil and Environmental Engineering and Geodetic Science, Ohio State University, Columbus, Ohio, USA. 16Department of Mineral Sciences, Smithsonian Institution, Washington, District of Columbia, USA. 17Department of Earth and Planetary Sciences, University of Tennessee, Knoxville, Tennessee, USA. 18Applied Physics Laboratory, Johns Hopkins University, Laurel, Maryland, USA. 19Niels Bohr Institute, University of Copenhagen, Copenhagen, Denmark. 20Max Planck Institute for Sonnensystemforschung, Katlenburg- Lindau, Germany. 21Department of Geosciences, State University of New York, Stony Brook, New York, USA. 1 of 35 dominate the floor of the Crater [Arvidson et al., 2006a]. It then drove onto the older Columbia Hills and has been traversing and making measurements of the terrains, rocks, and soils within the Hills since then (Figures 1?3 and A1?A8, Table 2). Results for the mission that include analyses of plains and initial Columbia Hills data (including West Spur and a portion of Husband Hill, up to and including measurements on the float rock, Backstay, sol 512, on the Cumberland Ridge), were reported in numerous papers in two Journal of Geophysical Research 2006 Special Issues. In this paper, a mission narrative is provided for the period when the rover left Backstay until it parked on the northern flank of Home Plate (sol 1447) to wait out its third Martian winter and associated low solar energy conditions (Figure 3). Selected scientific results are pre- sented in this paper that illustrate the synergistic use of the rover?s Athena Science Payload (Table 1) [Squyres et al., 2003] and that focus on understanding the geologic evolu- tion of the Columbia Hills and implications for the role of water in modifying crustal materials. This paper comple- ments papers that provide detailed findings about the geology, chemistry, and mineralogy of Husband Hill and the Inner Basin that are included in the third and fourth Journal of Geophysical Research Special Issues scheduled for publication in 2008. [3] Since publication of the initial Journal of Geophysical Research MER Special Issues in 2006, the Mars Recon- naissance Orbiter (MRO) has begun operations and the Columbia Hills have been imaged with the Compact Re- connaissance Imaging Spectrometer for Mars (CRISM) [Murchie et al., 2007], Context Imager (CTX) [Malin et al., 2007] and High Resolution Imaging Science Experi- ment (HiRISE) instruments [McEwen et al., 2007]. Analy- ses of selected MRO data are included in this paper to help define the regional-scale geomorphic and geologic contexts for Spirit?s observations and to extend the type of informa- tion that can be derived from orbit down to the fine details that can be observed from a mobile surface platform. Figure 1. CRISM-based false color infrared composite for the Columbia Hills (4.5 km wide at bottom margin) and surrounding cratered plains in Gusev Crater, with key features labeled. Spirit rover traverse locations from the landing site to the Low Ridge winter campaign site (where Spirit spent its second winter) located to the southeast of Home Plate are overlain as red line. Box denotes location for which a HiRISE image subset is shown in Figure 2. CRISM data with 18 m/pixel spatial from FRT00003192_07 using band 1098 nm for blue, 1518 for green, and 2528 nm for red are used in the composite. CTX image data with 6 m/pixel (frame PSP_001513_1654_XI_14S184W_061122) were used as the intensity in the color image to sharpen fine detail. North is to the top of this image. The striping is an artifact. Mars equirectangular projection. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 2 of 35 E12S33 Finally, implications for the extent of alteration of crustal materials on Mars by aqueous fluids are summarized on the basis of combined results from surface and orbital measure- ments for the Columbia Hills. Place names used in this paper are informal, with the exception of Meridiani Planum, Gusev Crater, and the Kau Desert. 2. Mission Narrative [4] The operational approach for driving, approaching targets, and making measurements with Spirit (and Oppor- tunity) and its Athena Payload (Table 1) has been detailed in previous papers [Arvidson et al., 2006a; Squyres et al., 2006] and will not be repeated here. Rather the focus is on a mission narrative, using the traverse locations overlain on MRO image data (Figures 1?2) to show the local and regional geomorphic context for the rover?s observations. Table 2 provides a detailed summary of the traverse andmeasurement campaigns for Spirit for the period relevant to this paper, Figure 3 provides a graphical view of operations as a function of time with Martian southern hemisphere seasons delineated, and Appendix A provides a detailed set of traverse and experiment site maps superimposed onto a HiRISE-based map. As shown in Figures 1?2 and Appendix A, Spirit?s traverses for the time period covered in this paper took place in the Columbia Hills, specifically Husband Hill and the Inner Basin. The Columbia Hills are a triangularly shaped complex of hills and intervening valleys that is embayed Figure 2a. HiRISE subframe covering Spirit?s traverse and experiment sites (yellow line) in the Columbia Hills. Boxes show traverse regions examined in detail in subsequent Figures 2b?2d. Plan view generated using PSP_001513_1655_red image. Image covers 1000 m in width. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 3 of 35 E12S33 Figure 2b. HiRISE subframe covering the western and southwestern portions of Husband Hill and the Cumberland Ridge and a portion of the Tennessee Valley. Traverses are shown in yellow, along with locations for each sol. Figure 2c. HiRISE subframe covering a portion of the southern slope of Husband Hill, including the dark El Dorado ripple field, bright ripples extending to the southeast, and bright outcrops to the east and northeast of the El Dorado feature. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 4 of 35 E12S33 by younger olivine-bearing volcanic plains [McCoy et al., 2008]. From West Spur, where Spirit entered the Columbia Hills, the distance to the eastern boundary with the plains is 1 km (Figure 1). Husband Hill, which was investigated in detail by Spirit, is0.5 km wide (E?W) and has a maximum elevation above the plains of 80 m (Figures 2a?2c). The Inner Basin is located to the south of Husband Hill and the northwest of McCool Hill, and is dominated by a series of interconnected low hills that include Home Plate, an oval feature 80 m wide that rises a few meters above the surrounding terrain (Figures 2a?2d). Mitcheltree Ridge and Low Ridge, oval to elongate hills that are located to the east and southeast of Home Plate, respectively, were also investigated by Spirit in some detail (Figures 2a?2d). [5] Spirit left the basaltic float rock, Backstay, on sol 513 and continued its ascent to the summit of Husband Hill, traversing along the western slopes and cutting at low angles across topographic contours (to avoid excessive wheel slippage) to reach the western portion of the summit on sol 580. Immediately after leaving Backstay the outcrop Methuselah was examined using the payload instruments. The outcrop Independence was then examined in detail, including use of the right front wheel to scuff the bedrock and remove dust and coatings [Clark et al., 2007]. Inde- pendence is a new rock type (relative to prior discoveries, [Squyres et al., 2006]) characterized by the lowest FeO content (3.8% weight) of any rock measured on Mars [Ming et al., 2008]. Spirit then encountered a suite of layered outcrops (Voltaire) and spent approximately 20 sols collect- ing in situ measurements for a series of targets on the outcrops while the remote sensing instruments observed dozens of targets within and beyond the outcrops (Table 3). The Voltaire experiments revealed a subclass of the Inde- pendence class of rocks (Assemblee) characterized by a high Cr2O3 content (2.9%) and a new class, Descartes, that is interpreted to be altered impact material (detailed in section 3 and by Ming et al. [2008]). The rover then continued its ascent to the top of Husband Hill, reached the summit and began a remote sensing campaign of the surrounding terrains from its high vantage point, including looking into the Inner Basin for safe paths for its descent to Home Plate. It then investigated an aeolian drift soil deposit (Lambert) before conducting observations on the float rock, Irvine, a subalkaline basalt rock class [McSween et al., 2006; Ming et al., 2008]. The Cliffhanger aeolian ripples at the head of the Tennessee Valley were then investigated, followed by the rock outcrop, Hillary (similar to the Watchtower rock class found on the northwestern slopes of Husband Hill [Squyres et al., 2006; Ming et al., 2008]), located on the eastern side of the summit. [6] The next phase of the mission was the descent into the Inner Basin by way of Haskin Ridge (Figure 2b). The Kansas Outcrop was characterized (similar to Hillary [Ming et al., 2008]), followed by a suite of measurements for olivine-rich outcrops (new Algonquin class rocks: Larry?s Bench, Seminole, Algonquin, Comanche [Morris et al., 2008; Ming et al., 2008]) before approaching the dark ripple field, El Dorado, located on the southeastern slopes of Husband Hill. The rover traversed to the edge of the ripple field and conducted remote sensing and in situ measure- ments of these materials before continuing its drive to Home Plate. During one of its drives, after leaving El Dorado, Spirit encountered difficulty in reaching a waypoint because of wheel slippage. The wheels churned up shallow subsur- face weakly bound rock or soil material that were found to Figure 2d. HiRISE subframe covering the Inner Basin, centered on Home Plate. Key features are labeled. Second and third winters correspond to locations where Spirit parked for these periods. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 5 of 35 E12S33 be enriched in hydrated ferric sulfate minerals (Arad depos- its) [Johnson et al., 2007; Yen et al., 2008; Wang et al., 2008]. Detailed measurements were made of these materials before the rover continued its drives toward Home Plate. [7] Home Plate, a partially eroded volcaniclastic con- struct [Squyres et al., 2007], was reached on sol 746 and a detailed measurement campaign was begun on the layered outcrop materials that showed fining upward sequences, along with extensive cross bedding (Barnhill, Posey (float), and Cool Papa Bell outcrops that define the Barnhill class of volcaniclastic rocks [Ming et al., 2008]). A float rock, Fuzzy Smith, was encountered on the northeastern edge of Home Plate, and measurements showed it to be a new rock class highly enriched in silica, titanium, and perhaps iron sulfide minerals relative to other rock measurements by Spirit [Squyres et al., 2007]. The rover then drove south through the Eastern Valley between the eastern edge of Home Plate and the western side of Mitcheltree Ridge. The intent was to head for the northern slopes of McCool Hill to find a suite of measurement locations for the rover to spend its second Mars winter. The need to park over the winter season was a consequence of the fact that Spirit is located at almost 15S latitude and during the winter solstice the sun is directly overhead at 25N latitude. Combined with accu- mulating dust on the solar panels, this situation called for a northerly vehicle tilt to maximize receipt of sunlight to maintain a reasonable battery charge. During its drive to McCool Hill, Spirit encountered another region with exten- sive wheel slippage associated with a gentle rise and terrace and excavated another high sulfate soil material (Tyrone). It Figure 3. Spirit mission timeline from sol 500 to 1500. RAT brush operations are shown as circles (RAT grind was inoperative during the period shown), wheel-based scuffs to expose rock substrate (Independence) and soils are shown as squares, and soil targets exposed by wheel motions during drives are shown as triangles. Southern hemisphere seasons are shown in color coded form. Dashed lines show periods when Spirit spent its second and third winters. Italicized text indicates winter campaign activities that were not RAT brush, scuff, or disturbed experiments. This figure is meant to complement more detailed listings of activities provided in Table 2. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 6 of 35 E12S33 became clear that traversing to McCool Hill would be difficult indeed, particularly when it became evident that the front right wheel drive motor had failed. Thus the decision was made to drive expeditiously to a nearby north-facing slope to spend the winter. The vehicle was commanded to drive to the northeast slope of Low Ridge and achieved an 8 northerly tilt, a value sufficient to survive its second winter season. [8] Spirit spent sols 805 to 1037 at the Low Ridge site during its winter campaign phase and conducted a suite of experiments focused on long duration Alpha Particle X-Ray Spectrometer (APXS) and Mo?ssbauer Spectrometer (MB) observations of soils and rocks within the Instrument Deployment Device (IDD) work volume, acquisition of a 13 filter high fidelity ??McMurdo Panorama?? using the Pancam imaging system (see Table 1 for instrument descrip- tions), photometry studies, monitoring surface and atmo- spheric targets for temporal changes using the various imaging systems (Table 1), and obtaining hundreds of emission spectra of the atmosphere and surface using the Mini-Thermal Emission Spectrometer (Mini-TES). The rock experiments included multiple in situ measurements of the platy buff-colored outcrops typified by Halley (rock class characterized by enrichment in hematite relative to other rocks [Morris et al., 2008; Ming et al., 2008]) and an attempt to use the Rock Abrasion Tool (RAT) brush to progressively bore into deeper and deeper soil horizons with measurements made at each horizon (Progress soil experi- ments). The inoperative right front wheel was dragged from Tyrone back to the winter campaign site as the rover drove backward. In a serendipitous turn of events, sulfate-rich Tyrone soil deposits excavated while the vehicle was in the Tyrone area were caught within the right front wheel cowling and released along the 40 m drive to Low Ridge, including deposits within the winter campaign work vol- ume. Long duration measurements were made on these materials (Berkner Island). Finally, long duration magnet measurements were also made during the winter campaign [Madsen et al., 2008]. [9] Leaving the winter campaign site was done with care toward the end of the winter season, first with a short bump to finely layered granular outcrops within Low Ridge (Graham Land, King George Island target) and then to a vesicular basalt float rock (Esperanza) also located on Low Ridge. The Esperanza measurements were cut short because of rising atmospheric dust opacity and thus decreasing solar energy on the panels. Spirit was sent on a short drive to a more northerly tilted terrain that also placed the vehicle for in situ measurements on the Troll outcrops (Montalva and Riquelme targets, a new rock class defined by high hematite and K2O contents [Morris et al., 2008; Ming et al., 2008]). Next Spirit was directed to drive back to within 10 m of the Tyrone disturbed soil deposits to acquire remote sensing and in situ data to further characterize the deposits and to search Table 1. Athena Payload and Engineering Camera Descriptions Instrument Key Parameters Mast Mounted Panoramic Camera (Pancam) Mulitspectral imager (0.4?1.0 mm) with stereoscopic capability; 0.28 mrad instantaneous field of view (IFOV); 16.8  16.8 field of view (FOV). Stereo baseline separation of 30 cm. External calibration target on rover deck. Thermal Emission Spectrometer (Mini-TES) Emission spectra (5?29 mm, 10 cm, 1 resolution) with 8 or 20 mrad FOV. Internal and external blackbody calibration targets. Instrument Deployment Device (IDD)-Mounted In Situ Package Alpha Particle X-Ray Spectrometer (APXS) 244Cm alpha particle sources, and X-ray detectors, 3.8 cm FOV. Mo?ssbauer Spectrometer (MB) 57Fe spectrometer in backscatter mode; Co/Rh source and Si-PIN diode detectors; field of view approximately 1.5 cm2. Microscopic Imager (MI) 30 mm/pixel monochromatic imager (1024  1024) with 6 mm depth of field. Rock Abrasion Tool (RAT) Tool capable of brushing or abrading 5 mm deep by 4.5 cm wide surface on rocks. Magnets Filter Located at front of rover within Pancam FOV. Weak magnet to cull suspended particles from atmosphere and examined by Pancam, MI, APXS, and MB. Capture Located at front of rover within Pancam FOV next to filter magnet. Strong magnet to cull suspended particles from atmosphere. Examined by Pancam, MI, APXS, and MB. Sweep Located next to Pancam calibration target. Intended to separate magnetic from nonmagnetic particles. Examined by Pancam. RAT Four magnets of different strengths built into RAT. Examined by Pancam and Hazcam when IDD points RAT toward cameras. Engineering Cameras Navigation Cameras (Navcam) Mast-mounted panchromatic stereoscopic imaging system with 0.77 mrad IFOV; 45 FOV, and 20 cm stereo baseline separation. For planning sequences. Hazard Avoidance Cameras (Hazcam) Front and rear-looking panchromatic stereoscopic imaging systems with 2 mrad IFOV; 123 FOV, 10 cm stereo baseline separation. For path planning and hazard avoidance during traverses. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 7 of 35 E12S33 Table 2. Major Activities for Spirit Organized by Sola Earth Date Sols Description of Activities Site at Start of Sol 13?14 Jun. 2005 513?514 Drive and ??Methuselah?? Outcrop targeted RS 110 15?27 Jun. 2005 515?527 Drive toward summit of ??Husband Hill??; RS 111?112 28 Jun. to 5 Jul. 2005 528?535 ??Independence?? Outcrop: approach, IDD: ??Franklin,?? ??Jefferson,?? and other targets; RS 112 6?13 Jul. 2005 536?543 Independence Outcrop: scuff, IDD, and RS ??Penn?? target; ??Independence Panorama?? 112 14?20 Jul. 2005 544?549 Drive toward summit of Husband Hill; RS 112 21?27 Jul. 2005 550?556 ??Voltaire??: ??Descartes?? Outcrop: approach, IDD, and RS ??Discourse?? target 113 27 Jul. to 2 Aug. 2005 556?562 Voltaire: ??Bourgeoisie?? Outcrop: bump, IDD, and RS ??Chic,?? ??Gentil_Matrice,?? and other targets 113 2?4 Aug. 2005 562?564 Voltaire: Haussmann Outcrop: bump, IDD, and RS ??Rue_Legendre,?? ??Rue_Laplace,?? and ??Sophie_Germain?? 113 5?12 Aug. 2005 565?572 Voltaire: ??Assemblee?? Outcrop: bBump, IDD, and RS ??Gruyere?? targets 113 13?23 Aug. 2005 573?582 Drive toward summit of Husband Hill; RS 113 23?25 Aug. 2005 582?584 Husband Hill Summit Panorama 114 25?29 Aug. 2005 584?588 ??Lambert?? soil: IDD and RS ??Couzy?? and ??Whymper?? targets 114 30?31 Aug. 2005 589?590 Drive toward ??Inner Basin Overlook #1??; RS 114 1?2 Sep. 2005 591?592 Drive toward ??Inner Basin Overlook #2??; RS 114 3 Sep. 2005 to 7 Sep. 2007 593?597 Magnet science; RS 114 8?12 Sep. 2005 598?602 Approach, IDD, and RS ??Irvine?? float target 114 13?21 Sep. 2005 603?611 ??Cliffhanger?? ripple: approach, scuff, IDD, and RS ??Landsend?? and ??Hang2?? targets, photometry campaign 114 22 Sep. to 4 Oct. 2005 612?623 Drive toward true summit of Husband Hill; RS; ??Everest Panorama?? 114 5?15 Oct. 2005 624?634 ??Hillary?? Outcrop: approach, IDD, and RS ??Khumjung?? and ??NamcheBazaar?? targets 114 16?22 Oct. 2005 635?641 Drive toward ??Haskin Upper Ridge??; RS 114?118 23?29 Oct. 2005 642?648 ??Kansas?? Outcrop: approach, IDD, and RS ??Kestral?? target 118 25 Oct. 2005 to 26 Oct. 2006 644?645 Anomaly precludes science activities ? 30 Oct. to 1 Nov. 2005 649?651 Drive toward Haskin Upper Ridge; RS 118 2?5 Nov. 2005 652?654 Remote sensing 118 6 Nov. 2005 655 Drive onto ??Haskin Lower Ridge?? 118 7?8 Nov. 2005 656?657 Remote sensing 119 9 Nov. 2005 658 Drive south toward ??Waypoint??; RS 119 10?14 Nov. 2005 659?663 ??Larry?s Bench?? Outcrop: approach, IDD, and RS ??Thrasher?? target 119 15?20 Nov. 2005 664?669 Drive south toward ??Waypoint??; RS 119 21?28 Nov. 2005 670?677 ??Seminole?? Outcrop: approach, IDD, and RS ??Osceola?? and ??Abiaka?? targets; ??Seminole Panorama?? 119 29 Nov. to7 Dec. 2005 678?686 Drive toward ??Algonquin?? Outcrop; RS 119 8?10 Dec. 2005 687?689 Algonquin Outcrop IDD and RS ??Iroquet?? target 119 12?18 Dec. 2005 690?696 Drive toward ??Comanche Spur?? Outcrop; RS 119?120 19?25 Dec. 2005 697?703 Comanche Spur Outcrop: approach, IDD, and RS ??Horseback,?? and ??Palomino?? targets 120 26?27 Dec. 2005 704?705 Drive toward ??El Dorado?? ripple; RS 120 28 Dec. to 1 Jan. 2006 706?710 El Dorado ripple: approach, scuff, IDD, and RS ??Gallant Knight,?? ??Edgar,?? and ??Shadow?? targets, photometry campaign 120?121 2?10 Jan. 2006 711?719 Drive toward ??Home Plate??; RS 121?122 11?13 Jan. 2006 720?722 Remote sensing 122 14?16 Jan. 2006 723?725 ??Arad?? disturbed soil: IDD and RS ??Samra?? and other targets 122 17?27 Jan. 2006 726?735 Drive toward Home Plate; RS 122?123 25?27 Jan. 2006 733?735 Dynamic brake anomaly and diagnostics ? 28?29 Jan. 2006 736?737 ??BuZhou?? and ??Pan_Gu?? float targets: IDD and RS 123 30 Jan. to 5 Feb. 2006 738?744 Drive toward Home Plate; RS 123 6 Feb. 2006 745 Remote sensing 124 7?11 Feb. 2006 746?750 ??Barnhill?? Outcrop: approach, IDD, and RS ??Ace,?? ??Pitcher,?? and ??Fastball?? targets 124 12?15 Feb. 2006 751?754 ??Posey?? Outcrop: approach, IDD, and RS ??Manager?? target 124 16 Feb. 2006 755 Drive toward Home Plate; RS 124 17?19 Feb. 2006 756?758 Remote sensing 124 E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 8 of 35 E12S33 Table 2. (continued) Earth Date Sols Description of Activities Site at Start of Sol 20?25 Feb. 2006 759?763 ??Cool_Papa_Bell?? Outcrop: approach, IDD, RS ??Stars,?? and ??Crawfords?? targets 124 26 Feb. to 1 Mar. 2006 764?767 Drive around Home Plate Rim; RS 124?125 2?5 Mar. 2006 768?771 ??Fuzzy Smith?? float: approach, IDD, and RS 125 6 Mar. to 5 Apr. 2006 772?801 Drive toward ??McCool Hill??; RS 125?126 13?15 Mar. 2006 779?781 Right front drive actuator fault and diagnostics ? 21 Mar. 2006 787 Right front wheel declared nonoperational ? 18 Mar., 24? 25 Mar., and 1 Apr. 2006 784, 790?791, 798 RS ??Tyrone?? disturbed soil 126 6?9 Apr. 2006 802?805 Drive toward and approach ??Low Ridge?? location for winter campaign experiments; RS 126 10?12 Apr. 2006 806?808 Remote sensing 126?127 13?15 Apr. 2006 809?811 ??Enderbyland?? IDD: ??Halley?? Outcrop target 127 16?22 Apr. 2006 812?818 Enderbyland IDD: ??Mawson?? soil target; Begin McMurdo Panorama 127 22 Apr. 2006 818 RS Tyrone disturbed soil 127 23?25 Apr. 2006 819?821 Remote sensing 127 26 Apr. to 3 May 2006 822?829 Enderbyland IDD and RS ??Progress?? soil target 127 30 Apr. 2006 826 RS ??Tyrone?? disturbed soil 127 4?5 May 2006 830?831 Enderbyland IDD and RS ??Progress1?? target 127 6?13 May 2006 832?838 Enderbyland IDD: ??Halley_Offset?? Outcrop target 127 14?16 May 2006 839?841 Enderbyland IDD: Progress1 brushed soil target 127 17 May 2006 842 IDD positioning test; RS 127 18?19 May 2006 843?844 Remote sensing 127 20?29 May 2006 845?854 Enderbyland: IDD and RS ??Progress2?? brushed soil target 127 24?26 May 2006 850?851 Anomaly precludes science activities ? 30 May to 4 Jun. 2006 855?860 Remote Sensing 127?128 4 Jun. 2006 860 Navcam photon transfer calibration experiment 128 5 Jun. 2006 861 Enderbyland IDD: ??Halley_Brunt?? Outcrop target 128 6?8 Jun. 2006 862?864 Remote sensing 128 8 Jun. 2006 864 RS Tyrone disturbed soil target 128 9 Jun. 2006 865 Rear Hazcam photon transfer calibration experiment 128 10?14 Jun. 2006 866?870 Enderbyland IDD: ??Progress3?? brushed soil target 128 12 Jun. 2006 868 Front Hazcam photon transfer calibration experiment 128 15?19 Jun. 2006 871?874 Remote sensing 128 20 Jun. to 4 Jul. 2006 875?889 Enderbyland IDD: Halley_Brunt Outcrop target 128 21 Jun. 2006 876 Microscopic Imager photon transfer calibration experiment 128 27 Jun. 2006 882 Left Pancam photon transfer calibration experiment 128 29 Jun. 2006 884 Right Pancam photon transfer calibration experiment 128 5 Jul. 2006 890 Mini-TES elevation actuator calibration 128 6 Jul. 2006 891 Remote sensing 128 7 Jul. 2006 892 Flight software uplink 128 8 Jul. 2006 893 RAT calibration; RS 128 9?11 Jul. 2006 894?896 Remote sensing 128 12?19 Jul. 2006 897?904 Enderbyland IDD: ??Halley_Brunt_Offset1?? Outcrop target 128 19 Jul. 2006 904 RAT unjamming activity 128 20?21 Jul. 2006 905?906 Remote sensing 128 22 Jul. 2006 907 Flight software build; RS 128 24 Jul. 2006 908 Enderbyland IDD: ??Palmer?? ripple target 128 25 Jul. 2006 909 Remote sensing 128 26 Jul. 2006 910 RAT cleaning and calibration; RS 128 27?28 Jul. 2006 911?912 Remote sensing 128 29 Jul. 2006 913 Enderbyland IDD: ??Palmer2?? ripple target 128 30 Jul. to 4 Aug. 2006 914?919 Remote sensing; complete McMurdo Panorama 128 5 Aug. 2006 920 Microscopic Imager photon transfer calibration experiment; RS 128 6?11 Aug. 2006 921?926 Remote Ssensing; begin filling-in McMurdo Panorama holes 128 7 Aug. 2006 922 RS Tyrone disturbed soil 128 12?14 Aug. 2006 927?929 Enderbyland IDD: ??Halley_Brunt_Offset2?? target 128 15?21 Aug. 2006 930?936 Remote sensing, including photometry campaign 128 16 Aug. 2006 931 Complete filling-in McMurdo Panorama holes 128 19 Aug. 2006 934 Begin McMurdo Deck Panorama 128 E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 9 of 35 E12S33 Table 2. (continued) Earth Date Sols Description of Activities Site at Start of Sol 22 Aug. 2006 937 Enderbyland IDD: Palmer target 128 23/06?26 Aug. 2006 938?941 Remote sensing 128 27 Aug. to 3 Sep. 2006 942?948 Enderbyland IDD: ??Halley_Brunt_Offset3?? target 128 31 Aug. to 1 Sep. 2006 945?946 Anomaly precludes science observations ? 4?9 Sep. 2006 949?954 Remote sensing 128 10?24 Sep. 2006 955?969 IDD capture and filter magnets; RS 128 14 Sep. 2006 959 RS Tyrone disturbed soil 128 17 Sep. 2006 962 Finish McMurdo Deck Panorama 128 20?22 Sep. 2006 965?967 Flight software boot and diagnostics ? 25 Sep. to 31 Oct. 2006 970?1005 MB filter magnet study; RS 128 25 Sep. and 8 Oct. 2006 970, 982 RS Tyrone disturbed soil 128 17?131 Oct. 2006 991?1005 Solar conjunction ? 18, 23, and 31 Oct. 2006 992, 997, 1005 RS Tyrone disturbed soil 128 1 Nov. 2006 1006 IDD capture and filter magnets; RS Tyrone disturbed soil 128 2?3 Nov. 2006 1007?1008 IDD and RS rock clast targets; IDD Mawson target 128 4?7 Nov. 2006 1009?1012 Remote sensing 128 5 Nov. 2006 1010 Bump bright soil tracks; RS 128 8?11 Nov. 2006 1013?1016 IDD: ??Berkner_Island_1?? disturbed soil target 128 12?17 Nov. 2006 1017?1021 IDD: ??Bear_Island?? disturbed soil target 128 17 Nov. 2006 1021 Pancam calibration target photometry experiment 128 18 Nov. 2006 1022 Bump layered outcrop; RS 128 19?22 Nov. 2006 1023?1026 Remote sensing 128 23?31 Nov. 2006 1027?1035 ??Graham_Land?? Outcrop: IDD and RS ??King_George_Island?? target 128 30 Nov. 2006 1034 IDD ??Clarence?? and ??Deception?? targets 128 1 Dec. 2006 1036 RS Tyrone disturbed soil; RS 128 3?18 Dec. 2006 1037?1052 Drive toward ??Esperanza?? float; RS 128 13 Dec. 2006 1047 RS Tyrone disturbed soil 128 20?28 Dec. 2006 1053?1061 IDD and RS ??Palma?? target on Esperanza float 128 28 Dec. 2006 1061 RS Tyrone disturbed soil 128 29 Dec. 2006 1062 Drive to location where solar arrays face sun 128 30 Dec. 2006 to 4 Jan. 2007 1063?1068 Atmospheric RS 128 5?25 Jan. 2007 1069?1089 ??Troll?? Outcrop: approach, IDD and RS ??Montalva?? target 128 16?28 Jan. 2007 1080?1091 Troll Outcrop: RS and IDD ??Riquelme?? and ??Zucchelli?? targets 128 21 Jan. 2007 1085 RS ??Contact?? and ??Londonderry?? targets 128 22 Jan. 2007 1086 IDD ??Svea?? and ??Maudhem?? targets 128 29 Jan. to 9 Feb. 2007 1092?1103 Drive toward Tyrone; IDD and RS ??Mount Darwin?? target 128 9 Feb. 2007 1103 Drive toward Troll 128 10 Feb. 2007 1104?1106 Automode 128 13?19 Feb. 2007 1107?1113 Approach and RS ??Bellingshausen,?? and ??Fabien?? and other outcrops 128 20 Feb. to 10 Mar. 2007 1114?1131 Drive toward Home Plate; IDD and RS; atmospheric RS 128 11?26 Mar. 2007 1132?1147 Approach, IDD, and RS ??Mitcheltree Ridge?? Outcrop: ??Torquas?? target 128 16 Mar. 2007 1137 MRO safe mode, run-out science submaster executed, photometry measurements 128 27?28 Mar. 2007 1148?1149 Drive toward Home Plate 128 29 Mar. to 20 Apr. 2007 1150?1171 Drive toward ??Madeline English?? Outcrop; IDD and RS 128?129 1?8 Apr. 2007 1153?1160 IDD and RS ??Elizabeth Mahon?? target 128 21?30 Apr. 2007 1172?1181 RS and IDD ??Everett,?? ??Slide,?? and ??Good Question?? Outcrop targets 129 1?2 May 2007 1182?1183 RS ??Gertrude_Weise?? disturbed soil 129 3?4 May 2007 1184?1185 Drive toward, IDD, and RS Gertrude Weise 129 5?24 May 2007 1186?1204 IDD ??Kenosha Comets,?? and ??Lefty Ganote?? targets 129 24 May 2007 1204 RS El Dorado ripples 129 25 May to 3 Jun. 2007 1205?1214 RS and IDD??Home Plate Outcrop?? ??Pesapallo,?? ??Superpesis,?? and ??June_Emerson?? targets 129 4?9 Jun. 2007 1215?1220 Approach, RS, and IDD Home Plate Outcrop ??Elizabeth Emery,?? ??Jane Stoll,?? ??Mildred Deegan,?? and ??Betty Wagner?s Daughter?? targets 129 10 Jun. 2006 to 23 Jun. 2007 1221?1234 Approach, IDD, and RS ??Nancy Warren?? Outcrop and target 129?130 13 Jun., 22 Jun., and 12 Jul. 2007 1224, 1233, 1252 Dust cleaning events 130 23 Jun. to 6 Jul. 2007 1234?1246 IDD and RS ??Eileen Dean?? disturbed soil; atmospheric RS 130 30 Jun. to 3 Jul. 2007 1240?1243 Stand down; atmospheric RS 130 E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 10 of 35 E12S33 for changes relative to measurements done before arriving at Low Ridge for the winter. After finishing these measure- ments, the rover focused on remote sensing and in situ work on the finely layered outcrops on the western side of Mitcheltree Ridge, most notably Torquas (rock class defined by high K2O, Zn, Ni contents and enrichment in magnetite [Morris et al., 2008; Ming et al., 2008]). Spirit was then commanded to approach and make remote sensing and in situ measurements on outcrops just to the east of Home Plate, including Elizabeth Mahon (new class of rock char- acterized by high SiO2 content [Squyres et al., 2008; Ming et al., 2008]), Madeline English, Everett and Good Question (latter two rocks define new classes on the basis of high MgO and magnetite contents for the former, and high SiO2 and low MnO contents for the latter [Morris et al., 2008; Ming et al., 2008]). During one of its backward drives Spirit?s right front wheel excavated light-toned soil deposits (Ger- trude Weise), which Mini-TES indicated and APXS meas- urements later confirmed have extraordinarily high silica contents [Squyres et al., 2008]. After completing measure- ments on these unusual deposits the rover drove to acquire detailed remote sensing and in situ measurements of the strata exposed on the eastern flank of Home Plate on sols 1205 to 1220 (Pesapallo, Superpesis, June Emerson, Eliz- abeth Emery). An outcrop identified as silica-rich from Mini-TES observations was then examined (Nancy War- ren), followed by another bright deposit excavated by the right front wheel (Eileen Dean). The vehicle was then commanded to drive over and crush rocks adjacent to Nancy Warren and broke open and obtained in situ obser- vations on the silica-rich targets Innocent Bystander and Norma Luker. [10] During an approximately 60 sol period when the vehicle was parked over Innocent Bystander waiting out the low solar energy conditions associated with a southern hemisphere dust storm, one or more of the Mini-TES mirrors was significantly contaminated by dust, reducing the spectral sensitivity of this instrument. After the dust storm, Spirit was commanded to approach and ascend onto Home Plate and obtain measurements designed to charac- terize the rocks on the top of Home Plate and rocks on the South Promontory. With the third winter season approach- ing, an increasing cover of dust on the solar panels, and hindered mobility on slopes due to the inoperative right front wheel, a decision was made to drive to the northern flank of Home Plate to achieve a maximum possible Earth Date Sols Description of Activities Site at Start of Sol 7 Jul. to 21 Aug. 2007 1247?1291 Nancy Warren Outcrop IDD ??Innocent Bystander?? and ??Norma Luker ??targets; RS, including photometry campaign 130 9?20 Aug. 2007 1279?1290 MI diagnostics 130 22 Aug. to 3 Sep. 2007 1292?1304 RS and drive toward Home Plate Mini-TES recalibration using ??Gertrude Weise?? disturbed soil 130 4?7 Sep. 2007 1305?1308 Drive toward Home Plate 130 7 Sep. 2007 1308 Reach Home Plate, RS 130 9?10 Sep. 2007 1309?1310 RS Home Plate 130 10?14 Sep. 2007 1310?1314 Drive toward Home Plate Site 2; RS 130?131 15 Sep. to 7 Oct. 2007 1315?1337 Drive toward Home Plate Site 3; RS; ??Home Plate South Panorama?? 131 25?30 Sep. 2007 1325?1330 IDD ??Texas Chili?? Outcrop target 131 16 Oct. 2007 1337?1345 Home Plate Site 3a feature: IDD ??Humboldt Peak?? float target 131 17?23 Oct. 2007 1346?1352 Drive toward Home Plate Site 4; RS 131 17 and 26?31 Oct. 2007 1346, 1355?1360 RAT diagnostics; RS 131?132 19?23 Oct. 2007 1348?1352 Long-baseline stereo off ??Home Plate?? 131 24?25 Oct. 2007 1353?1354 Drive toward Home Plate south off-ramp; RS 131 1?3 Nov. 2007 1361?1363 Drive toward Home Plate Site 5; RS 132 4?10 Nov. 2007 1364?1370 IDD ??Pecan Pie?? Outcrop target; RS 132 11?14 Nov. 2007 1371?1374 Drive toward Home Plate Site 6 132 15?20 Nov. 2007 1375?1380 Drive toward Home Plate Site 7; RS 132 20 Nov. to 19 Dec. 2007 1380?1408 Drive toward winter campaign site; atmospheric RS 132?133 20 Dec. to 15 Jan. 2008 1409?1434 IDD ??Chanute?? Outcrop target; Tuskegee Panorama 133 16?20 Jan. 2008 1435?1439 RS Fuzzy Smith float; atmospheric RS; RAT imaging 133 21 Jan. to 23 Mar. 2008 1440?1500 Atmospheric RS 133?134 26 Jan. to 6 Feb. 2008 1445?1456 IDD ??Freeman?? Outcrop target; RS ??Fuzzy Smith 2 Float,?? ??Winston Gaskins 2?? Outcrop target 133 26 Feb. 2006 to 20 Mar. 2008 1475?1497 IDD and RS ??Wendell Pruitt?? Outcrop and ??Arthur C. Harmon?? Soil targets; RS ??C.S. Lewis?? and Freeman Outcrop targets 134 27 Feb. 2008 1476 Begin Bonestell Panorama 134 aMeasurements were made on rock outcrops, float rocks, soils, and soils disturbed by the vehicle?s wheels. RS, remote sensing; IDD, Instrument Deployment Device. Note that the Mini-TES instrument capabilities were affected by dust on the mirror on sol 420, followed by additional accumulation during the course of the extended mission. Other acronyms defined in Table 1. Table 2. (continued) E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 11 of 35 E12S33 northerly tilt to survive the winter season. Spirit reached the site on sol 1408 and began a set of maneuvers to bump down the flank to follow the sun as it moved north toward its solstice position. Remote sensing and in situ measure- ments continued to be made as the vehicle moved down- slope, contingent upon available power. 3. Husband Hill: Voltaire Outcrop Campaign [11] The first scientific highlight to be discussed is the discovery of the layered Voltaire outcrops encountered after Spirit left the Independence Outcrop and continued its ascent to the summit of Husband Hill (Figure 2b and Table 3) [also see Clark et al., 2007]. Outcrops observed prior to discovery of the Voltaire sequence showed that bedding was largely conformable with the topography of the Hills, including outcrops on West Spur and the ensemble of outcrops found in Larry?s Lookout on the northwest flank of Husband Hill (Appendix A) [Squyres et al., 2006]. The observation that the outcrop pattern on Husband Hill con- forms to topography implies that the Hill is the geomorphic expression of an antiformal structure and that Spirit has largely examined the top of the section [McCoy et al., 2008]. On the other hand, the end-of-drive Pancam mosaic acquired on sol 549 showed a set of strata approximately 5 m long in a NE?SW direction and 2.5 m wide in a NW- SE direction, with a dip to the SE, i.e., dipping into the hill (Figure 4). The orientation of the strata was verified using a CAVE Virtual Reality Immersion System to view the out- crops at full scale and in three dimensions using Pancam and Navcam mosaics. This outcrop, which was named Voltaire because it was discovered on Bastille Day (14 July 2005), is truncated to the SW by a shallow trough and to the Table 3. Summary of the Voltaire Outcrop Measurement Campaign Sols Description of Activities 552 Started IDD work on Discourse target located on Descartes Outcrop with a MI mosaic and APXS integration. 553 Brush, MI, and APXS on Discourse. 554?555 MB integration on Discourse. 556 MI on two additional Descartes targets: Petitchou and Moncherie (dark clast). At end of sol the rover turned to face the rocks Sourir, Bourgeoisie, and Haussmann. 557 Started IDD work on Bourgeoisie Outcrop, with three MI mosaics and an APXS integration. Targets Gallant, Gentil, and Chic (APXS target), clast embedded in the outcrop. 558?559 MB integration on Chic target (Bourgeoisie) 560 Acquired MI, RAT brush, MI, and APXS data on Gentil Matrice target (Bourgeoisie). 561 MB integration on Gentil Matrice target. 562 Short MB integration on Gentil Matrice target. Sol finished with the rover turning to face Haussmann. 563 Three MI mosaics acquired on Haussmann Outcrop for targets Rue Legendre, Rue Sophie Germain, and Rue Laplace. An APXS measurement acquired on Rue Laplace. 564 Sol activities were lost when uplink did not make it to the rover. 565 Short drive to Assemblee. 566 MI and APXS integration on Gruyere target (Assemblee Outcrop). Target was too rough for RAT brush. 567?570 Four sols of MB integration on Gruyere target because of low Fe content. 571 MI and APXS integration on second Gruyere target to test whether clasts were source of high Cr in initial APXS measurement. Target name Gruyere_APXS. 572 IDD stowed in preparation of driving. 573 Drove away from Voltaire outcrops, looking back with Pancam during middrive. Figure 4. Portion of the sol 549 Pancam drive direction mosaic showing layered strata forming the Voltaire out- crops. The rocks strike from lower right to upper left (northeast to southwest) and dip into the hill (toward the southeast). Bourgeoisie, Haussmann, Descartes, and As- semblee are outcrops that were the focus of detailed in situ measurements by Spirit. Cocarde appears to have broken from Assemblee and moved slightly down hill. Both of these latter rocks have similar Mini-TES spectral emissivity signatures indicative of glassy materials. Enlightenment, Femey, and Revolution have emissivity signatures similar to one another and the rest of the Voltaire outcrops and also appear to be dominated spectrally by glassy materials. Pancam mosaic 2PP549ILFADCYL00P2352L777M2. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 12 of 35 E12S33 NE by a cover of soil and rocks (Figure 4). Specifically, detailed image analyses demonstrated the presence of a half dozen discrete layers striking 60 clockwise from north and dipping to the southeast (Table 4). The Voltaire out- crops may be a discrete me?lange block emplaced by impact or tectonic movements, or a tilted section of a more extensive exposure of bedrock. [12] An extensive campaign was undertaken by Spirit in which a number of targets on outcrops (Descartes, Bour- geoisie, Haussmann, and Assemblee) were examined using both the remote sensing and in situ instruments (Table 3). The outcrops exhibit two basic morphologic patterns. Des- cartes, Bourgeoisie, and Haussmann are characterized by relatively smooth, tabular appearances with well-defined bedding and joint planes (Figure 5). A number of sub- rounded to rounded clasts ranging in size from a centimeter to a few centimeters are contained in these tabular outcrops, i.e., the deposits are conglomerates (Figure 5). The exposed clast surfaces have been shaped into ventifacts by wind erosion. The Chic clast on Bourgeoisie was the target of Microscopic Imager (MI), APXS, and MB observations, along with nearby matrix materials (Discourse and Gentil Matrice) (Tables 1, 3, 5, and 6). Additional matrix measure- ments were made on the Haussmann and Descartes out- crops. The second morphologic form is represented by the top-most portion of the Voltaire Outcrop (Assemblee; Tables 3?5 and Figure 6). This conglomeratic rock exhibits a nodular or crumbly appearance and when examined with the MI shows numerous relatively small and well rounded clasts (typically < 0.5 cm across) (Figure 6b) [Clark et al., 2007]. Several other rocks with nodular textures similar to those for Assemblee can also be seen (e.g., Cocarde, Egalite; Figure 4), although as float rather than as outcrop. Assemblee was the only rock of this type for which MB, APXS, and MI data were acquired. [13] Pancam multispectral observations were obtained for the Voltaire outcrops and surrounding rocks and soils and representative spectra are shown for Descartes and Assem- blee surfaces in Figure 7. The absorption and scattering features for the spectral range covered by Pancam (0.4 to 1.0 mm) are controlled to first order by the abundance and textural characteristics of ferrous and ferric bearing minerals [e.g., Burns, 1993], including pyroxene, olivine, nanophase iron oxides, hematite, and goethite, all of which have been detected by Spirit?s MB during its measurements on the Columbia Hills [Morris et al., 2006, 2008]. The Pancam spectrum for the Descartes surface is brighter than the one for Assemblee and shows a steeper ferric absorption edge Table 4. Summary of Strikes and Dips Calculated for Voltaire Outcropsa Sol and Frame Number Strike (degrees) Dip to Southeast (degrees) 565 2R176524254RSDADAEP1312L0MZ N45E 35 565 2R176523021RSDA2P1301L0MZ N29E 23 565 2R176524254RSDADAEP1312L0MZ N48E 37 563 2F17634947RSLAD92P1121LOMZ N75E 46 aOrientations for the bedding planes were derived from unit vector surface normal data computed from stereo observations using regions of interest defined by inspection to isolate bedding surfaces. Figure 5. Pancam false color composite of the Descartes Outcrop oriented so that the bedding planes are parallel to the bottom of the image. Joints cut across the outcrop from lower right to upper left and can also be seen in the sol 549 approach mosaic (Figure 4). Locations of in situ observations are shown, including the Moncherie clast (bottom most labeled clast). Pancam frames 2P175278077ES- FAD40P2558L2M1, 2P175278161ESFAD40P2558L5M1, and 2P175278228ESFAD40P2558L7M1 were used to generate the mosaic. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 13 of 35 E12S33 between 0.4 to 0.8 mm. This is consistent with the MB and APXS observations that together show a threefold higher concentration of nanophase iron oxides and the presence of goethite (FeOOH) in Descartes as compared to Assemblee (Tables 5?6). The Descartes spectra show a band minimum between 0.9 to 1 mm, whereas the spectra for the Assemblee surface are relatively flat in this wavelength region. These patterns are consistent with the higher proportion of Fe- bearing minerals in Descartes (14.2% versus 6.4%, as FeO) based on APXS observations (summarized in Table 6) [Ming et al., 2008] and the detection of iron-bearing pyroxene for both outcrops from MB data (Table 5). Although great care must be exercised in comparing Pan- cam spectra with MB and APXS data because of the different sampling depths in this case the patterns in the data imply that all three instruments are sampling the same materials. [14] Mini-TES observations were acquired for a variety of rock targets during the extensive campaign of in situ observations on the Voltaire outcrops (Figures 8 and 9). The Mini-TES observations illustrate the synergistic use of the remote sensing elements of the Athena Payload (Table 1) in that the targeting for the observations took advantage of both Navcam and Pancam (including color) mosaics to cover the range of morphologic forms for the outcrops and float rocks within Spirit?s field of view. Figure 8 shows the Mini-TES ??footprints?? projected onto a portion of a Nav- cam mosaic taken when Spirit was sitting on the Voltaire outcrops. On the basis of emissivity patterns the rocks can be divided into five distinct spectral classes (Figure 9). First, many of the boulders uphill from the Voltaire Outcrop are spectrally similar to the Wishstone float rock observed earlier in the mission and found in many places on Husband Hill, as determined from Pancam and Mini-TES observa- tions (see Appendix A for Wishstone float rock location) [Farrand et al., 2006; Ruff et al., 2006]. The Wishstone-like emission spectra are dominated by stretching and bending vibrations of plagioclase feldspar of an intermediate com- position, as shown in Figure 9. A second and relatively rare class consists of boulders with spectra similar to the basaltic rock, Backstay (encountered earlier on Husband Hill, see Appendix A for location), based on olivine and pyroxene stretching and bending vibrational modes (Figure 9). A third and also relatively rare class of float rock is spectrally similar to the olivine-bearing basalt rocks that dominate the plains (i.e., similar to Adirondack and represented by Liberte; Figures 8 and 9). The abundance of Wishstone materials and their altered equivalents, Watchtower materi- als [e.g., Ming et al., 2008], on Husband Hill implies that the top of the antiformal stratigraphic section is dominated by these materials. Mapping by us shows that the Voltaire Outcrop is stratigraphically below Wishstone materials and includes the nearby Independence Outcrop (Appendix A). [15] Emissivity spectra for the Voltaire outcrops show a fourth and fifth pair of spectral classes that are distinctly different from those discussed in the previous paragraph. In particular, the Descartes class is characterized by broad, relatively featureless absorption in the low-wave-number region (<600 cm1) and dominates the spectral appearance for Descartes, Bourgeoisie, and Haussmann Outcrop obser- vations. The spectra are consistent with the presence of an amorphous silicate phase and also share similarities with the typical ??dust?? spectra identified in many places using Mini- TES data. Spectra for Assemblee form the fifth class and show a distinct emissivity minima at 1050 cm1 and 460 cm1 (Figure 9) and are similar to spectra for the outcrop, Clovis, on West Spur (see Appendix A for Clovis location and Ruff et al. [2006] for further spectral details). The broad nature of these two emissivity minima is similar to the spectra of glassy or amorphous silicate phases [e.g., Parke, 1974]. There are also spectra for float rocks near the Voltaire outcrops that match a mix of materials and are thought to represent Voltaire Outcrop materials that have been weathered and left exposed as boulders (Figure 8). [16] The Mini-TES footprint is too large to isolate Vol- taire Outcrop clast material. However, MB and APXS observations provide compelling evidence that the clasts are dominated by Wishstone-type materials (Tables 5 and 6). Table 5. MB-Based Percentage Iron Mineralogy for Key Targets From Morris et al. [2006, 2008] Name Olivine Pyroxene Ilmenite Chromite Nanophase Iron Oxide Magnetite Hematite Goethite Fe+3/Fetotal Descartes (A555RB0) 1 27 0 0 43 18 5 7 0.68 Chic (A559RB0) 26 25 18 0 23 7 2 0 0.31 Assemblee (A568RU0) 0 44 0 23 32 0 0 0 0.37 Cliffhanger (A609SU0) Cliffhanger_Hang2 13 41 0 0 30 7 9 0 0.45 El Dorado (A708SU0) Shadow 47 32 0 0 8 12 0 0 0.17 Halley (A836RU0) Halley_Offset 2 3 0 0 8 15 73 0 0.88 Esperanza (A1056RU0) Palma 4 45 0 0 4 45 1 0 0.40 Table 6. APXS Compositional Data From Ming et al. [2006, 2008] Oxides (wt %) Elements (mg/kg) SiO2 TiO2 Al2O3 FeO MnO MgO CaO Na2O K2O P2O5 Cr2O3 Cl SO3 Ni Zn Br Ge A552_OU_Descartes_Discourse 45.32 0.97 9.93 14.29 0.24 9.35 5.56 3.14 0.61 1.38 0.17 1.30 7.64 436 209 155 15 A566_OU_Assemblee_Gruyere 51.01 0.79 17.39 6.43 0.15 8.21 3.77 1.70 0.93 1.60 2.86 0.92 4.03 1248 244 65 22 A611_SU_Cliffhanger_Hang Two 47.73 1.20 12.34 10.77 0.22 7.24 7.13 3.60 0.51 2.10 0.13 0.78 6.16 168 155 104 4 A709_SU_El Dorado_Shadow 46.91 0.62 10.74 15.96 0.31 11.31 6.10 3.01 0.31 0.81 0.32 0.38 3.06 997 114 22 0 A833_SU_Enderbyland_Halley Center 45.30 0.90 8.73 17.97 0.24 9.31 5.30 2.71 0.60 0.90 0.19 0.86 6.67 777 2270 32 17 A1055_RU_Esperanza_Palma 47.9 1.05 8.40 20.2 0.38 8.45 5.57 3.40 0.52 0.91 0.20 0.47 2.36 395 368 181 19 E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 14 of 35 E12S33 This conclusion is strengthened by use of correspondence analysis applied to APXS elemental compositional data for rocks from the hills (Figure 10). Correspondence analysis is a powerful technique for exploring structure and relation- ships among samples and variables in a multidimensional data set. It is a form of principal component analysis in which normalization of the data matrix allows plotting of factor loadings for both samples and variables using the same scales [e.g., Arvidson et al., 2006a, 2006b]. In particular, analyses for the matrix material on Descartes, Bourgeoisie, and Haussmann show that these targets plot close to compositional origin (i.e., the average) of rocks analyzed in the Hills. The Chic clast (in the Bourgeoisie Outcrop) has a composition displaced toward the Wishstone sample location when projected onto the first two factor vectors (Figure 10). It also shows that Assemblee is enriched in Cr2O3, SiO2, K2O, and Al2O3 and depleted in FeO relative to the matrix material in the other Voltaire outcrops. In fact, removal of Cr2O3 and recomputing the factor loadings show that Assemblee and Independence have compositional similarities, a pattern also noted by Clark et al. [2007]. Assemblee is also enriched in Ni and Ge relative to the other matrix materials in the Voltaire outcrops (Table 6). [17] The amorphous material in the Voltaire outcrops detected by Mini-TES cannot be iron-bearing glass since this material would have also been detected by the MB instrument for Descartes, Bourgeoisie, and Haussmann, and Assemblee (and Clovis) and was not (Table 5) [Morris et al., 2006, 2008]. Rather the iron-bearing minerals in the outcrops (with the exception of clasts) are dominated by nanophase iron oxides and pyroxene. The Descartes matrix also has magnetite, hematite, and goethite present whereas Assemblee has chromite as a third phase. [18] The ensemble of data collected for the Voltaire experiments allows development of a working hypothesis for the formation and alteration of these outcrops. The conglomeratic nature of the outcrops, combined with the evidence for an amorphous or glassy component, argues for emplacement as an impact melt that incorporated local Wishstone materials, although emplacement as an energetic volcanic flow or pipe cannot be ruled out. Postemplacement alteration in an aqueous environment is indicated by the detection of goethite (FeOOH) in the Descartes Outcrop (Table 5). The presence of nanophase iron oxides, hematite, and goethite in Descartes and nanophase iron oxides in Bourgeoisie, and Haussmann outcrops, combined with the fact that none of the glassy or amorphous phases detected by Mini-TES are ferrous- or ferric-bearing, provide addi- tional clues for the alteration history of these materials. We envision a process of in situ alteration of the glassy phase in these rocks, releasing iron to form iron oxides and goethite, not unlike a terrestrial process in which allophane and iron oxides and oxyhydroxides are generated in soils weathered from basaltic rocks [Parfitt and Furkert, 1980] and glassy basaltic tephra [e.g., Morris et al., 2000]. Chromite in Assemblee (Table 5) may have remained immobile during this process. The Si and Ge enhancements and low FeO in Assemblee relative to the rest of the Voltaire measurements (Table 6) are consistent with the trends seen in Hawaiian soils formed from relatively intense aqueous weathering of basaltic rocks, i.e., SiO2 and Al2O3 and Ge concentrate in the soils while FeO is removed by aqueous processes [Morris et al., 2000; Kurtz et al., 2002; Ming et al., 2008]. Finally, we note that Schmidt et al. [2008] concluded from analyses of Mini-TES spectra that glassy or amor- phous components are indeed widespread in the Columbia Hills sites visited by Spirit, although no iron bearing glassy phases have been detected by MB [Morris et al., 2008]. Figure 6a. Pancam false color view of the Assemblee Outcrop showing the target Gruyere that was the focus of in situ measurements. Note the friable nature of this outcrop. The rock strikes from lower right to upper left (SW toNE) and dips into the hill (toward the SE). The Pancam frames used were 2P175540927ESFAD56P2566L2M1, 2P175541009ESFAD56P2566L5M1, and 2P175541077ES- FAD56P2566L7M1. Figure 6b. MI frame of Gruyere showing the presence of rounded, embedded clasts. Frame covers 3 cm across. Frame number 2M176609837EFFADAEP2936M2F1. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 15 of 35 E12S33 Thus the process described above may have been a common and widespread phenomenon that altered glassy deposits. 4. Inner Basin: Volcanic Rocks and Associated Deposits [19] Spirit entered the Inner Basin of the Columbia Hills after descending Husband Hill and Haskin Ridge, spending >800 sols exploring the landforms and deposits in and around the 80 m wide ovoidal plateau termed Home Plate (Figures 2a?2d and Table 2). Rock exposures on the flanks of Home Plate are dominated by volcanic tuff deposits that show evidence for energetic explosive emplacement, in- cluding cut and fill structures, cross bedding, and a ??bomb sag?? produced when a block was ejected into the atmo- sphere and impacted into deformable tuff deposits [Squyres et al., 2007; Lewis et al., 2008]. Interaction of subsurface magma with groundwater is the likely cause of the explo- sive volcanism. [20] Mitcheltree Ridge and Low Ridge (Figures 2 and 11), located to the east and southeast of Home Plate, respectively, are capped by vesicular basalt boulder fields and wind-blown soils (Figure 11). The rock, Esperanza, examined by Spirit after leaving the Low Ridge Winter Campaign site, is an example of one of these boulders (Table 2 and Figures 11?13). Examination of the MI coverage of Esperanza shows that the vesicles have been finely shaped by wind, forming a series of sharp edges typical of wind-sculpted vesicular basalt outcrops and boulders on Earth (Figure 12b). In fact the MI data show sand, the likely abrasive agent, sitting in one of the vesicles. MB observations of Esperanza indicate subequal amounts of iron within pyroxene and magnetite, with a minor component in nanophase iron oxides (Table 5). Pancam spectra for Esperanza are consistent with the presence and relative abundances of these minerals in that the spectra are dark (consistent with relatively high magnetite concentra- tion) and show a slight downturn at longer wavelengths consistent with the presence of pyroxene (Figure 7). Mini- TES spectra are dominated by the presence of pyroxene bending and stretching mode vibrations [see also Schmidt et al., 2008] and are similar to the spectra for Bounce Rock, a pyroxenite examined in detail by Opportunity in Meridiani Planum (Figure 13). [21] Thinly bedded, platy outcrops of granular materials composed of sand-sized grains are found near the bottom of both Low Ridge and Mitcheltree Ridge and the outcrop, Troll, located between the two Ridges (Figures 11 and 2d). Detailed mapping using Navcam panoramic images ac- quired from the Low Ridge winter campaign site, during traverses to and from Tyrone, and while Spirit was located in the Eastern Valley between Home Plate and the Ridges (Figure 2d), shows that these platy deposits are found on both western and eastern sides of the ridges and are dominated by dips into the Ridges [Lewis et al., 2007]. The deposits on the northern side of Low Ridge define dips Figure 7. Pancam spectra for a series of features discussed in this paper. The legend at the top of the figure denotes the feature names. Numbers in parentheses represent the Fe+3/Fetotal ratios derived from MB measurements for targets on the relevant features. The brighter spectra have higher ratios. Error bars represent 1 standard deviation about the mean values for the group of pixels used to generate the spectra. All the spectra show a strong ferric oxide absorption edge typical for Mars. Longer-wavelength features are also diagnostic of mineralogy and are discussed in detail in the text. R* is equivalent to Lambert albedo. The Pancam frames used are as follows: Descartes (p2558, Sol 551), 2P175278077IO- FAD40P2558L2C1; Assemblee (p2541, Sol 572), 2P177142010IOFADAEP2541L2C1; El Dorado (p2536, Sol 711), 2P189482458IOFAL02P2536L2C1; Cliffhanger (p2587, Sol 611), 2P180607674IO- FAEM9P2587L2C1; Halley (p2286, Sol 925), 2P208478741IOFAS00P2286L2C1; Esperanza (p2599, Sol 1070), 2P221351648IOFASCGP2599L2C2. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 16 of 35 E12S33 that wrap around and form the northern nose of a synclinal structure. Thinly bedded, platy outcrops are also evident on the eastern flank of Home Plate and dip to the west. Thus the outcrops on the Eastern Valley floor between Home Plate and the Ridges are exposed as the core of an antiformal structure. [22] The dominant materials exposed in the Eastern Valley, in addition to wind-blown soils, are platy, buff colored outcrops. Halley is one of these outcrops and was examined in detail while Spirit was parked for the winter at Low Ridge (Table 2 and Figure 11). MI images show that this platy outcrop is fine grained. MB data show that Halley?s iron-bearing minerals are dominated by hematite and that this outcrop has a very high Fe+3/Fetotal ratio (Table 5). Pancam spectra extracted for Halley and sur- rounding platy outcrops show a high overall albedo, pro- nounced ferric slope between 0.4 and 0.8 mm, an increasing reflectance with increasing wavelength out to 0.9 mm, a minor inflection at 0.9 mm, and a relatively sharp negative spectral slope between 0.9 and 1.0 mm (Figure 7). The sharp down turn for light-toned disturbed soils in the Eastern Valley observed by Pancam has been interpreted by Rice et al. [2008] as an O-H stretch overtone or a water combination band resulting from the presence of hydrated or hydroxlated mineral phases. On the basis of extensive APXS observations, Halley may contain calcium sulfate minerals, e.g., gypsum or anhydrite [Yen et al., 2008; Ming et al., 2008]. The ensemble of evidence for Halley implies that hermatite and hydrated or hydroxlated sulfate-bearing phases are present. [23] The thinly bedded, platy outcrop, Graham Land (King George Island target), is located stratigraphically above the Halley deposits and was examined by Spirit as it left the winter campaign site (Figure 11). MI data show that this outcrop is dominated by round, very coarse sand- sized grains, and MB data show that hematite dominates the iron-bearing mineralogy (Table 5 and Figure 14). Additional and similar deposits (Montalva and Riquelme) were exam- ined by Spirit when it parked at the adjacent Troll Outcrop and the ensemble of data again show that these deposits are platy, granular, and that iron-bearing materials are domi- nantly in hematite. In fact, correspondence analysis applied to MB data for all rocks found within the Inner Basin shows a progressive enrichment in hematite relative to other iron bearing minerals for the platy outcrops found on the Ridges and within the Eastern Valley (Figure 15). [24] As noted, the platy outcrops exposed in the Eastern Valley between Home Plate and the Ridges are largely covered by a thin veneer of wind-blown soil. In some locations the platy outcrops are covered not by soils but by clasts that exhibit a nodular appearance (Figure 16). These nodular materials, where examined by Spirit?s Mini- TES and APXS instruments, were found to be outcrops of silica-rich materials or debris fields of the same type of Figure 8. A subset of the Navcam mosaic acquired on sol 551 looking to the northeast, with color- coded footprint locations for acquisition of Mini-TES spectra overlain. Green colors correspond to the Descartes class spectrum shown in Figure 9. Magenta corresponds to the Assemblee spectral class. Red corresponds to a Wishstone-like, orange corresponds to a spectral mix of Assemble and Wishstone, and blue corresponds to an Adirondack-like spectrum. The Backstay spectral class is not shown on this mosaic. Note the dominance of Wishstone-like materials toward the uphill section of the image. Navcam mosaic 2NN551EFFADCYL56P0660L00M1. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 17 of 35 E12S33 materials crushed by the vehicle?s inoperative right-front wheel [Squyres et al., 2008, Figure 16]. Mini-TES spectra indicate the presence, in particular, of opaline silica, and APXS data for the Gertrude Weise disturbed soils show that the material is almost pure silica (90%) with the remaining component consisting largely of TiO2 [Squyres et al., 2008, Figure 17]. These materials are inferred to have been deposited by aqueous fluids under acid-sulfate low pH conditions by either dissolution and reprecipitation in-place or transport in solution to the depositional location [Squyres et al., 2008]. Additional support for the presence of acid- sulfate fluids is the presence of hydrated sulfate deposits in soils disturbed by Spirit?s wheels in the Inner Basin to the north of Home Plate (Arad feature) and to the east of Mitcheltree Ridge (Tyrone feature; Figures 2 and 11). Emissivity spectra indicate the presence of hydrated materi- als based on the presence of a 6 mm feature attributed to the fundamental bending mode of water, MB data show the presence of a ferric-sulfate phase, and APXS data show that SO3 increases with increasing SiO2 concentrations (Figure 17) [Morris et al., 2008; Yen et al., 2008; Wang et al., 2008]. [25] The results from the data collected by Spirit in and around Home Plate allow development of a model that focuses on the Inner Basin volcanic history and the role of aqueous fluids in emplacement and modification of the deposits. As noted, Home Plate has been interpreted to be a partially eroded volcaniclastic construct [Squyres et al., 2007]. Acid sulfate aqueous activity (vapor and/or fluids) occurred as the volcaniclastic deposits formed, interleaving silica-rich and sulfate-rich deposits, and altering some of the ash materials to hematite and other phases. For most of its history wind erosion has probably dominated changes in the Inner Basin, differentially stripping the materials to produce the landforms, outcrops, and soil exposures explored by Spirit. [26] The Kau Desert, Kilauea, Hawaii is offered as an Earth analog for the generation of volcaniclastic materials, lava flows, and formation of silica-rich and sulfate-rich deposits in the Inner Basin (Figure 18). In the Kau Desert, basaltic ash deposits are found interleaved with basaltic lava flows. Some of the ash deposits formed as rounded, well sorted, and oxidized accretionary lapilli produced when wet ash clouds caused nucleation of fine airborne ash into spherical sand grains. This is a plausible explanation for the finely layered, platy, granular deposits evident in the King George Island Outcrop and elsewhere in the Inner Basin ridges (Figure 14). Opaline silica encrustations are common in the Kau Desert and form in the vicinity of steam vents by dissolution of rock and in-place precipitation of opaline silica, and as case-hardened, but friable coatings on ash deposits created as silica-rich solutions evaporated when they reached the surface [Malin et al., 1983; Schiffman et al., 2006; K. Seelos et al., Silica in a Mars Analog Environment: Ka?u Desert, Kilauea Volcano, Hawaii, man- uscript in preparation, 2008]. Further, in some locations acid-sulfate rich solutions have thoroughly altered basaltic materials and left behind silica-rich residues. Sulfate depos- its (e.g., primarily gypsum, minor amount of jarosite) also form near steam vents, although the minerals are retained primarily where protected (beneath overhangs or within internal cavities within lava flows) from rainfall and disso- lution (Seelos et al., manuscript in preparation, 2008). 5. Coordinated Analyses of Orbital and Spirit- Based Data Sets [27] The previous sections of this paper have highlighted the extensive exploration and measurement campaigns conducted by Spirit in the Columbia Hills and focused on Figure 9. Mini-TES spectra (in black) from the Voltaire region compared with laboratory and other Mini-TES spectra in colors. Descartes spectra have a significant dust component as evident from the scaled Gusev dust spectrum (brown) and the relatively featureless low-wave-number region (<600 cm1) is consistent with a mixture containing an amorphous silicate phase like basaltic glass (magenta; scaled laboratory). Assemblee spectra are dominated by an amorphous silicate phase like basaltic glass (magenta) and among all Mini-TES spectra from Gusev crater, most resemble Clovis class rocks (green). Wishstone spectra are dominated by intermediate plagioclase (labradorite shown in red; scaled) and clearly match the type example (blue, an average of four spectra) from earlier in the mission. Backstay and Adirondack spectra (orange and purple, respectively) compare favorably to the subset of float rock spectra shown. Adirondack spectra are dominated by olivine, as shown by the scaled laboratory-based spectrum (cyan) that is an average of 60% forsteritic olivine and 35% forsteritic olivine compositions. Adirondack was examined early in the mission on the plains [Arvidson et al. 2006a]. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 18 of 35 E12S33 two examples that show that water was involved in alter- ation of crustal materials: the Voltaire outcrops and the emplacement and modification of volcanic materials in the Inner Basin. The discovery of evidence for extensive aqueous alteration is in contrast to what was found by Spirit during its exploration of the volcanic plains that surround and embay the Hills. Specifically the plains are dominated by olivine-bearing basaltic float rocks and wind-blown soils that are weakly altered relative to the rocks in the Hills [Arvidson et al., 2006a; Haskin et al., 2005; McSween et al., 2008; Morris et al., 2008; Ming et al., 2008]. The question is: Can the evidence for aqueous alteration in the Columbia Hills also be detected from orbit? [28] Analysis of Mars Global Surveyor Thermal Emis- sion Spectrometer (TES) data [e.g., Martinez-Alonso et al., 2005] and Mars Express OMEGA hyperspectral imager data (0.4 to 5 mm) [Lichtenberg et al., 2007] for the Gusev plains are also consistent with the presence of slightly oxidized basalt sands mixed with and covered to varying extent with dust. Neither orbital instrument can resolve landforms within the Columbia Hills since the pixel size for TES is 3 km and at best 350 m for OMEGA. Thus data from TES and OMEGA cannot be used to test the hypothesis that Spirit?s observations in the Columbia Hills of glassy or amorphous deposits, goethite, hematite, opaline silica, and hydrated sulfates can also be detected from orbital observations. On the other hand, the CRISM hyperspectral imager on MRO acquires Full Resolution targeted (FRT) mode data from 0.4 to 4.0 mm (545 bands, 18 m/pixel, 10 km frame width) and is able to resolve many of the features within the Columbia Hills, including Husband Hill, El Dorado, and the Inner basin (Figure 1). In this section of the paper, reduction and analysis of CRISM observations are detailed and conclu- sions drawn about what controls the spectral signatures of the Columbia Hills at the spatial scale sampled by this instrument. [29] Several CRISM Full Resolution targeted (FRT) mode observations were acquired of the Columbia Hills and surrounding areas while Spirit obtained near simulta- neous atmospheric optical depth measurements using the Pancam cameras to image the sun at 0.4 and 0.8 mm and Mini-TES to obtain temperature profiles of the lower atmosphere. These observations and dust and ice aerosol radiative properties based on historical trends from TES data were used with the DISORT radiative transfer code [Stamnes et al., 1988] to model CRISM?s spectral radiances. Atmospheric carbon dioxide, water vapor, carbon monox- ide, and associated Rayleigh scattering and discrete gas absorption bands for CO2, H2O, and CO were included in the computations, along with aerosol scattering and absorp- tion. Procedures were implemented to retrieve surface Figure 10. APXS-based factor 1 versus 2 plot from a correspondence analysis run for rocks examined on Husband Hill. This plane captures 83% of the variance of the APXS data set and shows how rock analyses relate to one another and which elements provide ??finger prints?? or distinguishing characteristics for the samples. For example, Independence is enriched in SiO2, K2O, and Al2O3, whereas Wishstone is enriched in CaO, Na2O, P2O5, and TiO2 relative to the average composition for rocks examined on Husband Hill. The rock analyses shown in red are for matrix materials (Discourse on the Descartes Outcrop, Gentile Matrice on the Bourgeoisie Outcrop, and Rue LaPlace on the Haussmann Outcrop), whereas the blue color corresponds to Chic, a clast in the Bourgeoisie Outcrop. Note that the matrix materials plot close to the composition average for the rocks, whereas Chic is displaced toward Wishstone. Assemblee is highly enriched in Cr2O3 and is enriched in SiO2, K2O, and Al2O3 and plots as a very chemically distinct rock relative to other rocks examined on Husband Hill. APXS data from Ming et al. [2006] and Ming et al. [2008]. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 19 of 35 E12S33 Lambert albedos using DISORT-based simulations and regressions for each wavelength band between modeled CRISM radiances and a suite of input gray surface albedos, following the methodology outlined by Arvidson et al. [2006b] for modeling OMEGA data over the Opportunity site. The retrieved surface spectra were examined for residuals associated with changes in band pass character- istics relative to prelaunch calibrations and incomplete removal of atmospheric carbon dioxide and water vapor. Runs with updated band pass values and atmospheric conditions relative to historical trends and rover-based observations allowed convergence on the proper atmospher- ic model within several iterations. [30] We concentrate on CRISM FRT00003192_07 ac- quired over the Columbia Hills and surrounding plains while Spirit was located at the Low Ridge winter campaign site (Figure 1). Detailed analysis of the CRISM spectra for the plains does not show any spectral evidence of the phyllosilicates, hydrated sulfates, or opaline silica deposits found elsewhere on the planet using OMEGA and CRISM observations [e.g., Gendrin et al., 2005; Arvidson et al., 2005; Poulet et al., 2005; Mustard et al., 2008; Milliken et al., 2008]. A detailed search was also conducted using the CRISM data over the Columbia Hills for spectral signatures from (1) Voltaire and Voltaire-like materials (e.g., water combination bands at 1.4 and 1.9 mm, metal-OH features from allophane-like materials between 2 and 2.5 mm); (2) opaline silica signatures expected from deposits such as the disturbed soils in Gertrude Weise (e.g., the broad 2.2 mm Si- OH absorption and the 1.9 mm H2O combination band detected using Airborne Visible and Infrared Imaging Spec- trometer (AVIRIS) data in the Kau Desert, Hawaii (Seelos et al., manuscript in preparation, 2008) and from CRISM data for selected plains around Valles Marineris [Milliken et al., 2008]); and (3) multiple H2O combination bands associated with hydrated sulfates (e.g., water combination bands be- tween 1 and 2.5 mm). None of these signatures was detected, even when precisely locating Spirit?s experiment sites and examining single pixel spectra for these regions. Instead, the Columbia Hills CRISM spectra are dominated by the ferric-rich dust (spectrally dominated by nanophase iron oxides), olivine, and pyroxene, as will be detailed in the next several paragraphs. The data do show the ubiquitous 3 mm band found across Mars and associated with adsorbed or absorbed water molecules. The lack of vibra- tional bands associated with hydrated or hydroxlated min- erals (i.e., items 1?3 above) is not surprising considering that the length scale for the Voltaire Outcrop is only 5 m Figure 11. Portion of McMurdo Pancam panorama acquired from the Low Ridge winter campaign site looking to the northeast. The light-toned Tyrone disturbed soils can be seen in the distance, along with tracks leading to and from Tyrone, and the light-toned soils spilled from the right front wheel cowling during Spirit?s backward drive from Tyrone to the winter site. Berkner Island is the light-toned soil target examined in detail by Spirit with its in situ instruments. King George Island is the platy outcrop target that dips into Low Ridge and that was examined by Spirit, along with the vesicular basalt boulder Esperanza immediately after leaving the campaign site in the spring. Halley and Bear Island were also examined in detail as part of the winter campaign. The Troll Outcrop, located in the upper left portion of the figure, was another location for detailed measurements after leaving the campaign site. Platy outcrops typified by King George Island wrap around Low Ridge and form a synformal structure. Color image using the 0.43 for blue, 0.53 for green, and 0.60 mm for red. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 20 of 35 E12S33 by 2.5 m and the rocks are surrounded and partially covered by wind-blown soil (Figure 4). In addition, the opaline silica and sulfate soils examined by Spirit were discovered only after the vehicle exposed them during drives (Figures 11 and 16), while the silica-rich nodular outcrops are small and heavily contaminated by wind-blown soil. The deposits may be widespread, but they are hidden from CRISM by a cover of wind-blown soil. Finally, no signatures expected from phyllosilicate minerals were detected for any spectra extracted from the Columbia Hills. [31] Detailed examination of the CRISM data for the Columbia Hills regions traversed by Spirit shows that the spectral end-members are represented by the top of Hus- band Hill and the upper slopes of Tennessee Valley for the brightest area and the El Dorado ripple field for the darkest area (Figures 1, 2, and 19). On the basis of imaging data acquired while Spirit was at the summit of Husband Hill, combined with examination of the HiRISE data covering the summit and Tennessee Valley, it is clear that the upper portion of Tennessee Valley and the northern portion of the summit are covered by light-toned ripples that have migrated from the NW, i.e., up the valley (Figures 2a and 2b) [Sullivan et al., 2008]. Spirit examined one of these ripples (Cliffhanger) during its summit experiments (Table 2 and Figures 2b and 20). The experiments included measure- ments of undisturbed and scuffed soils in the ripple. MB observations of the undisturbed (Hang2) and scuffed (Lands End) ripple soils indicate in order of decreasing abundance: pyroxene, nanophase iron oxides, olivine, hematite, and magnetite (Figure 20 and Table 5). Spirit also conducted similar experiments on the eastern edge of the El Dorado Figure 12a. Portion of the McMurdo Pancam panorama shown in Figure 11 enlarged to show details of Esperanza, interpreted to be a vesicular basalt boulder. The IDD target Palma is located on the left side of Esperanza out of site of the view shown. A second boulder is evident to the upper left of Esperanza and is interpreted to be a fine-grained rock shaped by wind into a ventifact. Esperanza is approximately 0.20 m across. Figure 12b. MI mosaic of Esperanza illustrating the extent to which wind-blown sand and dust has shaped the surface into a set of sharp curvilinear ridges. Note the sand sitting on the bottom of one of the vesicles. Frame covers 6 cm across. Mosaic 2MMA53IOFASORTAFP2936M222F1 with a filtering and contrast enhancement applied to minimize loss of detail from shadows. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 21 of 35 E12S33 ripple field (Table 2 and Figures 2c and 21), with MB measurements from the undisturbed surface (Shadow) indi- cating in order of decreasing abundance: olivine, pyroxene, magnetite, and nanophase iron oxides (Table 5). Mini-TES spectra extracted for these surfaces indicate a dominance of olivine for the El Dorado area based on the bending vibrational modes evident between 650 to 400 cm1 and a dust dominance for the Cliffhanger ripple surfaces based on the overall spectral shape (Figure 22). Pancam spectra retrieved for Cliffhanger and El Dorado undisturbed surfaces are similar in overall shape to the CRISM spectra and consistent with a dominance of nanophase iron oxides in the visible wavelengths, olivine and pyroxene for longer wavelengths for the El Dorado spectra, and nanophase iron oxides and pyroxene for the light-toned ripples that domi- nate the western summit of Husband Hill and the upper Tennessee Valley (Figures 7 and 19). The El Dorado spectra also indicate a thin coating of dust that becomes translucent or more forward scattering with increasing wavelength, thus allowing the darker mafic sand to spectrally dominate. This phenomenon produces a negative slope as documented analyses of OMEGA data by Lichtenberg et al. [2007] for the Gusev plains and shown in the laboratory by Fischer and Pieters [1993] and Johnson and Grundy [2001]. [32] Sullivan et al. [2008] show that El Dorado is a ripple field that accumulates a thin coating of dust that locally is removed by dust devils. The light-toned ripples on the top of Husband Hill, on the other hand, are more coarse grained and interpreted to be active only during rare high velocity wind events capable of moving the coarse particles and otherwise develop a uniform dust cover [Sullivan et al., 2008]. An optically thick dust cover is certainly consistent with the observation that the Pancam and Mini-TES spectra for Cliffhanger are dominated by dust, whereas the MB data show the presence of nanophase iron oxides (a dust com- ponent) and pyroxene, i.e., MB has a greater penetration depth than either Pancam or Mini-TES and can see more of the underlying pyroxene. Sullivan et al. [2008] also hypoth- esize on the basis of the presence of angular grains (i.e., not Figure 13. Mini-TES spectra for Esperanza and 12 other vesicular rocks from Low Ridge are shown in black (red is the average) and overlain with the pyroxene-rich Bounce rock spectrum (in green; this rock is a pyroxenite from Meridiani Planum and was observed by Opportunity) to demonstrate a spectral dominance by pyroxene. Pyroxene- rich rocks represent another spectral class of rock observed by Mini-TES that includes those dominated by glass or amorphous phases as represented by the average Assemblee spectrum (blue), the plagioclase-dominated Wishstone spectrum (purple), and the olivine-dominated spectrum represented by Adirondack basalt (magenta). Figure 14. Microscopic Imager view ofKingGeorge Island, a friable, platy deposit (see Figure 11) of round, uniformly sand sized grains. Average grain size is 1 mm. Mosaic covers 6 cm in width. Wind-blown soil can be seen surrounding the rock at the top and bottom of the mosaic. The composition of this outcrop is mainly SiO2, followed in relative abundance by FeO, MgO, and Al2O3 (Table 6). The iron mineralogy is dominated by hematite (43%; Table 5 and Figure 15), implying alteration under oxidizing conditions to remove iron from ferromagnesian silicates to form hematite. The dark lines are MI poker shadows. Mosaic generated from frames 2M217894337IFFAS20P2956M2F1, 2M217894630IF- FAS20P2956M2F1, 2M217894945IFFAS20P2956M2F1, and 2M217895270IFFAS20P2956M2F1 acquired on sol 1031. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 22 of 35 E12S33 Figure 15. MB-based correspondence analysis of all rocks in the Inner Basin showing hematite enrichment for the friable, platy outcrops exposed on the floor of Eastern Valley and Low and Mitcheltree Ridges. Numbers refer to the fraction of the iron that is contained within hematite. Montalva is stratigraphically below the Riquelme Outcrop at Troll. A series of measurements were made on different sections of Halley and are shown, along with King George Island. Hillary is a rock from the summit of Husband Hill with a fairly large amount of nanophase iron oxide, magnetite, and hematite [Morris et al., 2008]. Factors 1 and 3 are used because this projection shows the hematite trend better than other planes. Factors 1 and 3 capture 67% of the variance in the data set. Figure 16. Pancam false color mosaic showing the Nancy Warren, Innocent Bystander, and Norma Luker targets in detail. Innocent Bystander and Norma Luker represent rocks broken apart by wiggling (using the operative azimuthal actuator) and dragging Spirit?s right front wheel over them. Note the debris field produced when the rover backed up after doing its crushing. The dark rock labeled vesicular basalt is typical of numerous clasts and boulders shown to be of basaltic composition. The Pancam frames used were 2P235913627ESFAU37P2378L2M1, 2P235913690ESFAU37P2378L5M1, 2P235913733ES- FAU37P2378L7M1, 2P235913941ESFAU37P2378L2M1, 2P235914094ESFAU37P2378L5M1, and 2P235914221ESFAU37P2378L7M1. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 23 of 35 E12S33 Figure 17. Factors 1 versus 2 plot from correspondence analysis applied to APXS data for Inner Basin targets. Note that the SiO2 and SO3 vectors plot toward the top of the diagram and that key targets follow these vectors and show progressive enrichments in both SiO2 and SO3, although the targets split into SiO2- and SO3-dominated trends. Numbers and labels in yellow are for SO3 concentrations, whereas those in green are for SiO2 concentrations. Arad (Samra) is the disturbed soil with the highest abundance of SO3 (35%) and Kenosha Comets in the Gertrude Weise disturbed soil has the highest abundance of SiO2. This projection captures 87% of the variance of the multivariate data set. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 24 of 35 E12S33 Figure 18. Color image from the Kau Desert, Hawaii, showing differentially eroded accretionary lapilli basaltic ash deposits draped over vesicular basalt flow outcrops and boulders. Rock hammer for scale. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 25 of 35 E12S33 rounded by extensive erosion and transport) that the Cliff- hanger ripples contain a significant contribution from local outcrops in Tennessee Valley. In fact, correspondence anal- ysis applied to elemental abundances determined for soils by Spirit shows that the Cliffhanger ripples have a chemical affinity for Wishstone rocks (Figure 23). As noted in section 3 of this paper, Wishstone materials dominate the rock population on Husband Hill on the basis of Mini-TES spectra. Wishstone (and Watchtower, its altered equivalent [Ming et al., 2008]) will add feldspar (Figure 9, from Mini- TES data) to the light-toned ripples in the Tennessee Valley and the northwestern side of the Husband Hill summit. Feldspar would be spectrally neutral and thus not uniquely detectable in the Pancam and CRISM wavelength intervals. Thus, the orbital and surface observations combined pro- vide a self-consistent picture of what is controlling the spectral variety at the 18 m/pixel scale relevant to the CRISM measurements, i.e., regional-scale aeolian mixing of dust and sand with local materials. [33] Examination of CRISM spectra for the Columbia Hills shows a smooth variation in albedo and shape consis- tent with mixing between the end-members described in the last paragraphs and shown in Figure 19. This is not Figure 19. CRISM spectra retrieved from FRT00003192? 07 for light-toned ripples on Husband Hill and Tennessee Valley and the dark El Dorado ripple field, overlain Pancam spectra retrieved for undisturbed surfaces on the Cliffhanger and El Dorado ripples. Data are shown between 0.4 and 2.5 mm only to emphasize comparisons with Pancam data, although retrievals extended to 4.0 mm. The spectral data are consistent with control by iron-bearing minerals, with strong ferric absorption edges shortward of 0.8 mm, broad absorptions between 0.8 and 1.5 mm due to olivine and pyroxene, and a negative slope longward of 0.8 mm for the El Dorado spectrum due to a thin dust cover that becomes translucent at long wavelengths to reveal the underlying mafic sand signature. The upturn for the longest Pancam wavelength for the Cliffhanger ripple is interpreted to be a consequence of a large dust component for this surface (10 cm wide patch) as compared to the CRISM data (3  3 pixel averages at 18 m/pixel) for the two spectra. Gap in CRISM data 0.7 mm is a nonrecoverable portion of the spectrum where two detectors join. Gap just longward of 1 mm is the join between the S and L CRISM detectors [Murchie et al., 2007]. Pancam spectra extracted from scenes quoted in Figure 7 caption. Figure 20. Hazcam frame covering Cliffhanger ripple scuff experiments on the summit of Husband Hill. Hang2 is the location for the MB and APXS undisturbed surface measurements. View is looking toward the northwest into the Tennessee Valley and shows the set of light-toned ripples that have migrated toward the summit. Frame 2F180078494RSLAEM9P1214L0MZ acquired on sol 605. Figure 21. Hazcam frame covering El Dorado scuff experiments and looking back toward Husband Hill. Shadow is the location for the MB undisturbed surface measurements. Frame 2F189393623RSLAL00P1121L0MZ acquired on sol 710. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 26 of 35 E12S33 Figure 22. Mini-TES spectra are shown for Cliffhanger and El Dorado ripple surfaces, together with spectra from a visually bright and dusty hollow on the rim of Bonneville Crater (Figure 1) and dark ripples within that crater. The dark ripple fields have spectra controlled by olivine (particularly the long- wavelength region, compare to Figure 9 for Adirondack). The light-toned ripple surfaces are dominated by dust signatures. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 27 of 35 E12S33 Figure 23. APXS-based correspondence analysis for all soils examined by Spirit. The Wishstone float rock analysis is also shown. The appended ??_d?? means that the soil has been disturbed or excavated by Spirit?s wheels. The range of natural soil surfaces varies from El Dorado (basaltic sand, with both disturbed and undisturbed samples shown) to Lambert Whymper (basaltic sand and dust). Eileen Dean is located at an extreme position because of its abundance of Cr2O3 and MgO and as noted in the text has been altered. Cliffhanger and Pequod Doubloon are soils that have the addition of local Wishstone materials. Boroughs and Big Hole are subsurface trench soil analyses showing an enrichment in SO3. Data from Gellert et al. [2006] and Ming et al. [2008]. Captures 78% of the variance of the data set. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 28 of 35 E12S33 Figure 24. MB-based correspondence analysis showing trends from basaltic sand with a small amount of dust indicated by high abundance of olivine, pyroxene, and magnetite (e.g., El Dorado ripple field) to basaltic sand with a significant amount of dust delineated by nanophase iron oxides, e.g., Cliffhanger Hang2 on the Cliffhanger light-toned ripple field. Numbers represent Fe+3/Fetotal ratios. Chromite has not been included in the correspondence analysis since this mineral was only found in the Assemblee rock [Morris et al., 2008]. The _d for soils refers to scuffed soils or soils disturbed by Spirit?s wheels during drives. Cliffhanger Hang2 is the undisturbed surface for Cliffhanger, whereas Cliffhanger LandsEnd_d corresponds to the measurement within the scuff zone. Eileen Dean is a highly altered soil exposed by the rover?s wheels, as noted in the text. The factors 1 versus 2 plane projection accounts for 78% of the multidimensional data set variance. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 29 of 35 E12S33 surprising considering that Spirit has mainly encountered wind-blown soils on West Spur, Husband Hill, and the Inner Basin, i.e., the mineralogical variations and aqueous alter- ation associated with the various rock types encountered by Spirit are not evident because the rock areal footprint is small relative to soil and dust covers. A spectral dominance by iron bearing minerals is also evident when comparing the patterns for MB observations for soils examined by Spirit to the end-members found in the CRISM spectra (Figures 19 and 24). The Cliffhanger undisturbed surface MB observa- tion (Hang2) has the highest ratio of Fe+3/Fetotal (0.45) and the highest abundance of nanophase iron oxides of any soil (including the plains soils) whereas El Dorado (0.17) has the lowest ratio and highest proportion of olivine and pyroxene (Table 5). The vast majority of soils fall on a mixing line between El Dorado and Hang2 with olivine and pyroxene dominating the former and nanophase iron oxide in much higher abundance in the latter. Magnetite pulls the soil data off a simple mixing line, as expected, with an extreme case defined by the disturbed soil, Eileen Dean, found close to Nancy Warren (Figure 16). But, this material would not be evident from orbit because it was found in one of Spirit?s wheel tracks. Eileen Dean, with its unusually high concentration of magnetite, MgO, Cr2O3, Zn, Ni, and Cl, unusually low NaO and Al2O3, and the presence in Mini-TES of a 6 mm water bending mode vibration, is unusual in many respects and probably represents yet another type of aqueous alteration not observable from orbit because of the ubiquitous cover of wind-blown sand [Morris et al., 2008; Ming et al., 2008]. 6. Conclusions and Implications [34] Spirit has shown extensive evidence for interaction of water and crustal materials over its 1500 sols of exploration. This includes Voltaire, altered impact or volca- nic rocks on Husband Hill, and the formation of volcani- clastic materials with hematite, sulfate, and opaline silica enrichment produced by aqueous processes in and around Home Plate in the Inner Basin. On the other hand, orbital spectral observations by the CRISM hyperspectral imager (0.4?4.0 mm) are dominated by the presence of iron-bearing phases. The discrepancy between extensive evidence for aqueous alteration discovered by Spirit and the dominance of iron-bearing minerals from orbit is resolved when it is realized that windblown deposits dominate the traverse sites by areal extent and that the evidence for alteration observed by Spirit occur in outcrops that are too small and/or mostly buried to be resolved in the 18 m/pixel orbital data. OMEGA and CRISM observations show the presence of phyllosilicates, hydrated sulfates, and opaline silica else- where on Mars where these deposits are exposed on spatial length scales properly sampled by the spatial footprints for these sensors. The fact that the Columbia Hills shows evidence for extensive aqueous alteration when examined in detail over much smaller length scales (i.e., from Spirit) Figure A1. Overview of Spirit?s traverses. Image covers 1900 m in width. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 30 of 35 E12S33 bodes well for continued and detailed observations by future rover missions that are focused on ??following the water?? and evaluating whether or not the planet was once habitable. We suggest that older terrains on Mars are likely to have been ubiquitously altered by aqueous processes, increasing the likelihood that the planet was once habitable and that the evidence has been preserved. Appendix A [35] In this Appendix we provide detailed traverse informa- tion for Spirit, overlain on HiRISE image PSP_001513_1655_ red, projected to an equirectangular map base. To precisely locate the rover on any given sol the ensemble of rover observations was used by us to locate the position on the HiRISE image using a combination of nearby and horizon landmarks. The locations were cross-checked against a bundle-adjusted set of locations derived from stereo image analysis by Li et al. [2008]. The presentation includes an overview map (Figure A1) showing the traverses, together with boxes that show enlargements in Figures A2?A8. Sols, sites, and key terrain features are shown on the enlargements, although the high density of experiment sites in EasternValley Figure A2. Traverses are shown across West Spur. Figure A3. Traverses are shown across the northern portion of Spirit?s travels on Husband Hill. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 31 of 35 E12S33 (Figure A8) precludes delineation of each location. These overlays should be used in combination with Tables 2 and 3, Figure 3, and the description of operations provided in the main body of the paper to understand what Spirit has accomplished. Note that the box labels refer to relative locations of the boxes on Husband Hill and not to absolute cardinal positions. The detailed traverses and measurements conducted in Eastern valley are not possible to show in detail on a HiRISE base map. Figure A4. Traverses are shown across the southwestern portion of Spirit?s travels on Husband Hill. Figure A5. Traverses are shown across the southeastern portion of Spirit?s travels on Husband Hill. E12S33 ARVIDSON ET AL.: MER SPIRIT OVERVIEW AND SELECTED RESULTS 32 of 35 E12S33 Figure A6. Spirit?s traverses are shown across the Haskin Ridge and areas to the south. Figure A7. 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S., et al. (2008), Hydrothermal processes at Gusev Crater: An evaluation of Paso Robles class soils, J. Geophys. Res., 113, E06S10, doi:10.1029/2007JE002978.  R. E. Arvidson, R. Greenberger, E. A. Guinness, A.Wang, and S.Wiseman, Department of Earth and Planetary Sciences, Washington University, 1 Brookings Drive, St. Louis, MO 63130, USA. (arvidson@rsmail.wustl.edu) J. F. Bell III, S. W. Squyres, and R. J. Sullivan, Department of Astronomy, Cornell University, 610 Space Sciences Building, Ithaca, NY 14853, USA. N. A. Cabrol, NASAAmes/SETI Institute, Moffett Field, CA 94035, USA. B. C. Clark, Lockheed Martin Corporation, 12999 West Deer Creek Canyon Road, Littleton, CO 80125, USA. L. S. Crumpler, New Mexico Museum of Natural History and Science, 1801 Mountain Road NW, Albuquerque, NM 87104, USA. W. H. Farrand, Space Science Institute, 4750 Walnut Street, Suite 205, Boulder, CO 80301, USA. R. Gellert, Department of Physics, University of Guelph, MacNaughton Building, Gordon Street, Guelph, ON, Canada N1G 2W1. W. Goetz, Max Planck Institute for Sonnensystemforschung, 2 Max- Planck-Strasse 2, D-37191 Katlenburg-Lindau, Germany. J. A. Grant, Center for Earth and Planetary Studies, National Air and Space Museum, Smithsonian Institution, P.O. Box 37012, Washington, DC 20013, USA. K. E. Herkenhoff and J. R. Johnson, U. S. Geological Survey, 2255 North Gemini Drive, Flagstaff, AZ 86001, USA. J. A. Hurowitz and A. S. Yen, Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109, USA. G. Klingelho?fer, Institut fu?r Anorganische und Analytische Chemie, Johannes Gutenberg-Universita?t, Duesbergweg 10-14, D-55099 Mainz, Germany. K. W. Lewis, California Institute of Technology, 1200 East California Boulevard, Pasadena, CA 91125, USA. R. Li and M. Schmidt, Department of Civil and Environmental Engineering and Geodetic Science, Ohio State University, 470 Hitchcock Hall, 2070 Neil Avenue, Columbus, OH 43210, USA. M. B. Madsen, Niels Bohr Institute, University of Copenhagen, Blegdamsvej 17, DK-2100 Copenhagen, Denmark. T. J. McCoy, Department of Mineral Sciences, Smithsonian Institution, P.O. Box 37012, Washington, DC 20013, USA. S. M. McLennan, Department of Geosciences, State University of New York, 255 Earth and Space Sciences Building, Stony Brook, NY 11794, USA. H. Y. McSween and J. Moersch, Department of Earth and Planetary Sciences, University of Tennessee, 306 Earth and Planetary Sciences Building, Knoxville, TN 37996, USA. D. W. Ming, R. V. Morris, and C. Schro?der, Johnson Space Center, NASA, 2101 NASA Parkway, Houston, TX 77058, USA. S. L. Murchie, Applied Physics Laboratory, Johns Hopkins University, 11100 Johns Hopkins Road, Laurel, MD 20723, USA. S. W. 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